대한화학회지 (Journal of the Korean Chemical Society)

  • 제46권3호
  • /
  • Pages.213-218
  • /
  • 2002
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

1.4-Dibora-2,5-cyclohexadiene 유도체를 리간드로 갖는 니켈 Double-decker 착물의 합성

Synthesis of Nickel Double-decker Complexes Containing 1,4-Dibora-2,5-cyclohexadiene Derivatives as Ligand

  • 엄재국 (계명대학교 자연과학부 화학전공)
  • Eom, Jae Guk (Department of Chemistry, College of Natural Science, Keimyung University)
  • 발행 : 2002.06.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

(${\eta}^5$-Cyclopentadienyl)(${\eta}^6$-1,2,3,4-tetramethyl-1,4-dibora-2,5-cyclohexadiene)Ni(5)는 cyclopentadienyl (carbonyl)-nickel dimer와 1,2,3,4-tetramethyl-1,4-dibora-2-cyclohexene (1)을 반응시켜서 주생성물로 얻었다. Di-allyl nickel과 2,3-diethyl-1,4-dimethyl-1,4-dibora-2-cyclohexene (2)을 -20$^{\circ}C$에서 반응시켜서 bis[${\eta}^6$-2,3-dimethyl-1,4-diethoxy-1,4-dibora-2,5-cyclohexadiene]nickel (6) 착화합물을 15% 수율로 생성하였다. 그리고 야-allyl nickel과 2,3-dimethyl-1,4-diethoxy-1,4-dibora-2-cyclohexene (3)을 역시 -20$^{\circ}C$에서 반응시켜서 22% 수율로 bis[${\eta}^6$-2,3-dimethyl-1,4-diethoxy-1,4-dibora-2,5-cyclohexadiene] nickel (7)을 생성하였다. 이들 double-decker 착화합물들은 불안정하여 분리하기 어려웠으며, NMR, MS, 원소분석 등으로 확인하였다.

(${\eta}$5-Cyclopentadienyl)(${\eta}$6-1,2,3,4-tetramethyl-1,4-dibora-2,5-cyclohexadiene)Ni (5) was synthe-sizedas a main product by the reaction of cyclopentadienyl(carbonyl)nickel dimer and 1,2,3,4-tetramethyl-1,4-di-bora-2-cyclohexene (1). Di-allyl nickel reacted with 2,3-diethyl-1,4-di-methyl-1,4-dibora-2-cyclohexene (2) at -20$^{\circ}C$ to give bis(${\eta}$6-2,3-diethyl- 1,4-dimethyl-1,4-dibora-2,5-cyclohexadiene)nickel (6) in the yield of 15%. By the reaction of di-allyl nickel and 2,3-dimethyl-1,4-diethoxy-1,4-di- bora-2-cyclohexene (3) at -20$^{\circ}C$ bis[${\eta}$6-2,3-dim-ethyl-1,4-diethoxy-1,4-di- bora-2,5-cyclohexadiene]nickel (7) was obtained in 22% yield. These double-decker complexes were difficult to separate because of their unstabilities and were identified by ESR, NMR, MS and ele-mental analysis, etc.

키워드

참고문헌

  1. Timms, P. L. J. Am. Chem. Soc. 1968, 90, 4585. https://doi.org/10.1021/ja01019a014
  2. Herberich, G. E.; Hessner, B.; Huttner, G.; Zsolnai,L. Angew. Chem. Int. Ed. Engl. 1981, 20, 472. https://doi.org/10.1002/anie.198104721
  3. Herberich,G. E.; Hessner, B.; Beswetherick, S.; Howard,J. A. K.; Woodward, P. J. Organomet. Chem. 1980,192, 421. https://doi.org/10.1016/S0022-328X(00)81234-6
  4. Camp, R. N.; Marynick, D. S.; Graham, G. D.; Lipscomb,W. N. J. Am. Chem. Soc. 1978, 100, 6781. https://doi.org/10.1021/ja00489a054
  5. Binger, P. Angew. Chem. Int. Ed. Engl. 1968, 7, 286.
  6. Uhm, J. K.; Hu, D.; Zenneck, U.; Pritzkow, H.; Siebert,W. J. Korean, Chem. Soc. 1990, 34, 490.
  7. Uhm,J. K. Ph.D. Dissertation, Univ. Heidelberg, 1987.
  8. Woerner, K. F.; Uhm, J. K.; Pritzkow, H.; Siebert, W.Chem. Ber. 1990, 123, 1239. https://doi.org/10.1002/cber.19901230605
  9. Jonas, K.; Kruger, C. Angew. Chem., 1980, 92,513. https://doi.org/10.1002/ange.19800920705
  10. Jonas, K. Angew, Chem. Int. Ed. Engl., 1983, 22, 716. https://doi.org/10.1002/anie.198307161
  11. Cordes, J. F. Chem. Ber., 1962, 95, 3084. https://doi.org/10.1002/cber.19620951236
  12. Fischer, E. O.; Palm. C. Chem. Ber. 1958, 91, 1725. https://doi.org/10.1002/cber.19580910823
  13. Tilney-Bassett, J. F. J. Chem. Soc.[London] 1961,577. https://doi.org/10.1039/jr9610000577
  14. Schuetze, M. Angew. Chem. 1958, 70, 697. https://doi.org/10.1002/ange.19580702206
  15. Uhm, J. K.; Roemich, H.; Wadepohl, H.; Siebert, W. Z.Naturforsch. 1988, 43 Teil B, 306.
  16. Siebert, W.; Ender, U.; Herter, W. Z. Naturforsch.1985, 40b, 326.
  17. Edwin, J.; Boehm, M. C.; Chester,N.; Hoffmann, D. M.; Hoffman, R.; Pritzkow, H.; Siebert,W.; Stumpf, K,; Wadepohl, H. Organometallics,1983, 2, 1666. https://doi.org/10.1021/om50005a033
  18. Kuhlmann, T.; Siebert, W. Z. Naturforsch.1984, 39b, 1046.
  19. Siebert, W. Angew. Chem. 1985,97, 943.
  20. Uhm, J. K.; Siebert, W. Bull. Kor. Chem. Soc. 1996, 17,206.
  21. Lauher, J. W.; Elian, M.; Summerville, R. H.; Hoffmann,R. J. Am. Chem. Soc. 1976, 98, 3219. https://doi.org/10.1021/ja00427a028
  22. Uhm, J. K.; Siebert, W. Bull. Korean Chem. Soc., 1992,13, 528.
  23. Vollhardt, K. P. C.; Angew. Chem. Int. Ed. Engl.1984, 23, 539. https://doi.org/10.1002/anie.198405393
  24. Uhm, J. K.; Park, Y. B.; Byun, S. I.; Lee, H.; Kwak, Y. W.; Kim, T. J. J. Kor. Chem. Soc. 1991, 35, 410.
  25. Uhm, J. K.; Lee, J. O.; An, H. W. J. Kor. Chem. Soc.1997, 41, 608.
  26. Noeth, H.; Wrackmeyer, B. NMR-Spectroscopy ofBoron Compounds, Springer-Verlag Heidelberg, 1978.

피인용 문헌

  1. 1,4-Dibora-2,5-Cyclohexadiene 유도체를 리간드로 갖는 철 착물의 합성 vol.47, pp.2, 2002, https://doi.org/10.5012/jkcs.2003.47.2.179