대한화학회지 (Journal of the Korean Chemical Society)

  • 제46권2호
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  • Pages.139-144
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  • 2002
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  • 1017-2548(pISSN)
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  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
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니켈 촉매를 이용한 1,1'-Bis(dimethylsilyl)ferrocene과 Carbonyl 화합물의 Silylation 반응

Nickel Catalyzed Silylation Reaction of Carbonyl Compounds with 1,1'-Bis(dimethylsilyl)ferrocene

  • 공영건 (경기대학교 자연과학부 화학과) ;
  • 이정현 (경기대학교 자연과학부 화학과)
  • 발행 : 2002.04.20
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초록

니켈 착물을 촉매로 사용한 1,1´-Bis(dimethylsilyl)ferrocene [1]과 carbonyl 화합물 -benzaldehyde, 4-cyanobenzaldehyde, trimethylacetaldehyde, acetophenone과 benzophenone-은 3-oxa-2,5-disilacyclo-1,1′-ferrocene을 생성하였다. 이와 대비되게 동일한 반응조건에서 화합물 [1]과 isobutyraldehyde의 반응에는 1,1′-bis(dimethylsilyl)ferrocene의 Si-H 결합에 2개의 aldehyde ligand가 이중 삽입된 생성물이 형성되었다.

The nickel-catalyzed reation of 1,1'-bis(dimethysilyl)ferrocene[1] with carbonyls such as benzaldehyde, 4-cyaonbezaldehyde, trimethylacetaldehyde, acethon, and benzophenone afforded 3-oxa-2,5-disilacyclo-1,1'-ferrocene. In contrast, the reation of [1] with isobutyraldehyde under the same reation condition yielded the diinsertion products formed via the insertion of two aldehyde ligands into the Si-H bond of 1,1'-bis(dimethy)ferrocene.

키워드

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피인용 문헌

  1. Hydrosilylation and double silylation of carbonyl compounds with 1,1′-bis(dimethylsilyl)ferrocene using nickel- and platinum-catalysts vol.48, pp.11, 2007, https://doi.org/10.1016/j.tetlet.2007.01.009
  2. 니켈/백금 촉매에 의한 1,1'-Bis(dimethylsilyl)ferrocene과 Aldehydes의 선택적 Silylation 반응 vol.51, pp.3, 2002, https://doi.org/10.5012/jkcs.2007.51.3.232
  3. 백금/니켈 촉매를 이용한 1,1'-Bis(dimethylhydrosilyl)ferrocene과 Alkynes, Alkenes의 선택적 Hydrosilyation 반응 vol.54, pp.1, 2002, https://doi.org/10.5012/jkcs.2010.54.01.027