Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
권호 표지

Chromatographic Separation of Lithum Isotopes by Hydrous Managanese(Ⅳ) Oxide

가수된 산화 망간(Ⅳ)에 의한 리튬 동위원소의 크로마토그래피적 분리

  • Kim, Dong Won (Department of Chemistry, Chungbuk National University)
  • 김동원 (충북대학교 자연과학대학 화학과)
  • Published : 20010600
Download PDF
⟨ Previous Next ⟩

Abstract

Separation of lithium isotopes was investigated by chemical ion exchange with a hydrous manganese(IV) oxide ion exchanger using an elution chromatography. The capacity of manganese(IV) oxide ion exchanger was 0.5 meq/g. The heavier lithium isotope was enriched in the solution phase, while the lighter isotope was enriched in the ion exchanger phase. The separation factor was determined according to the method of Glueckauf from the elution curve and isotopic assays. The separation factor of $^6Li^+$-$^7Li^+$ isotope pair fractionation was 1.018.

용리 크로마토그래피를 사용하여 가수된 산화 망간(Ⅳ)이온교환체로 화학적 이온교환을 통하여, 리튬 동위원소를 분리하는 연구를 하였다. 산화 망간(Ⅳ)이온교환체의 이온교환 용량은 0.5meq/g이었다. 무거운 리튬 동위원소는 용액상에, 그리고 가벼운 동위원소는 이온교환 수지상에 농축되었다. 분리인자는, Glueckauf의 방법으로 용리곡선과 동위원서 분석 값들로부터 구하였다. $^6Li^+$-$^7Li^+$ 동위원소쌍의 분별로부터 얻은 분리인자의 값은 1.018이었다.

Keywords

References

  1. J. Colloid Interface Sci. v.43 Breeuwsma, A.;Lyklema, J.
  2. Envioron. Sci. Technol. v.2 Posse;t, h. S.;Anderson, F. J.;Weber, Kr.;W. J.
  3. Ann Arbor Science Publishers Inc. In Adsorption of Inorganics at Solid-Liquid Interface Rubin, A. J.;Mercer, D. L.;Anderson, M. A.(ed.);Rubin, A. J.(ed.)
  4. Ana; Chem. v.46 Gadde, R. R.;Laitinen, H. A.
  5. Separ. Sci. Technol. v.34 Takeuchi, H.;Oi, T.;Hosoe, M.
  6. J. Nucl. Sci. Technol. v.21 Nishizawa, K.;Watanabe, H.;Ishini, S.;Shinagawa, M.
  7. Technical Information Center, U. S. Energy Research and Development Administration Report ERDA-tr-32, Translation of Romanian Report Vasaru, G.
  8. Separ. Sci. Technol. v.20 Symons, E. A.
  9. Dritte Aufl. Walter de Gruyter onenqustauscher Dorfner, K.
  10. Trans. Faraday Soc. v.51 Glueckauf. E.
  11. Trans. Faraday Soc. v.54 Glueckauf. E.
  12. J. Radioanal Nucl. Chem v.220 Kim, D. W.;Hing, C. P.;Kim, C. S.;Jeong, Y. K.;Jeon, Y. S.;Lee, J. K.
  13. Inorg. Nucl. Chem. v.35 Okuyama, K.;Okada, I.;Saito, N. J.
  14. Separ. Sci. Technol. v.31 Kondoh, A.;Oi, T.;Hosoe, M.
  15. A. Naurforsch. v.27 Heumann, K. G.;Lieser, K. H.
  16. Separ. Sci. Technol. v.27 Oi, T.;Ofino, H.;Hosoe, M.;Kakihana, H.
  17. Separ. Sci. Technol. v.34 Ooi, K.;Miyai, Y.;Makita, Y.;Kanoh, H.
  18. MLM-3695 Jepson, B. E.;Novotny, M. A.;Evans, W> F.
  19. J. Nucl. Sci. Technol. v.20 Fujine, S.;Saito, K.;Shiba, K.
  20. Separ. Sci. Technol. v.26 Oi, T.;Kawada, K.;Hosoe, M.;Kakihana, H.
  21. Zh. Fiz. Khim. v.48 Klinskii, G. D.;Knyazev, D. A.;Vlasova, G. I.
  22. Naturforsch. v.29 Aaltonen, J.;Heumann, K. G.;Pietila, P. Z.
  23. Angew. Chem. v.92 Heiummann, K. G.;Schiefer, H. P.
  24. J. Inorg. Nucl. Chem. v.38 Lee, D. A.