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Excitation Temperature and Electron Number Density Measured for End-On-View Indectively Coupled Plasma Discharge


Abstract

The excitation temperature and electron number density have been measured for end-on-view ICP discharge. In this work, end-on-view ICP-AES equipped with the newly developed “optical plasma interface (OPI)” was used to eliminate or remove the neg ative effects caused by end-on-plasma source. The axial excitation temperature was measured using analyte (Fe I) emission line data obtained with end-on-view ICP-AES. The axial electron number density was calculated by Saha-Eggert ionization equilibrium theory. In the present study, the effects of forward power, nebulizer gas flow rate and the presence of Na on the excitation temperature and electron number density have been investigated. For sample introduction, two kinds of nebulizers (pneumatic and ultrasonic nebulizer) were utilized.

Keywords

References

  1. Inductively Coupled Plasma in Analytical Atomic Spectrometry(2nd ed) Montaser, A.;Golightly, D. W.
  2. Inductively Coupled Plasma Emission Spectroscopy, Part Ⅰ& Ⅱ Boumans, P. W.
  3. Inductively Coupled Plasma in Analytical Atomic Spectrometry(3nd ed.) Hasegawa, T.;Umemoto, M.;Haraguchi, H.;Hsiech, C.;Montaser, A.;Montaser, A.(eds.);Golightly, D. W.(eds.)
  4. Appl. Spectrosc. v.31 no.137 Kalnicky, D. J.;Fassel, V. A.;Kniseley R. N.
  5. Spectrochim. Acta v.49B no.817 Zahang, H.;Hsiech, C.;Ishii, I.;Zeng, Z.;Montaser, A.
  6. J. Anal. At. Spectrom. v.15 no.419 Iacone, L. I.;Masamba, W. R. L.;Nam, S.;Zhang, H.;Minnich, M. G.;Okino, A.;Montaser, A.
  7. J. Quant. Spectrosc. Radiat. Transfer v.33 no.197 Eddy, T. L.
  8. Spectrochim. Acta v.40B no.1387 Huang, M.;Hieftje, G. M.
  9. Spectrochim. Acta v.43B no.841 Marshall, K. A.;Hieftje, G. M.
  10. Appl. Spectrosc. v.38 no.245 Scheeline, A.;Zoellner, M.
  11. Spectrochim. Acta v.B31 no.365 Boumans, P. W. J. M.;DeBoer, F. J.
  12. Spectrochim. Acta v.34B no.333 Falk, H.;Hoffman, E.;Jaeckel, J.;Ludke, C.
  13. Appl. Spectrosc. v.35 no.380 Houk, R. S.;Svec, H. J.:Fassel, V. A.
  14. Spectrochim. Acta v.40B no.579 Blades, M. W.;Caughlin, B. L.
  15. Spectrochim. Acta v.45B no.731 Olesik, J. W.;Den, S. J.
  16. Spectrochim. Acta v.40B no.987 Caughlin, B. L.;Blades, M. W.
  17. Spectrochim. Acta v.40B no.423 Furuta, T.;Nojiri, Y.;Fuwa, K.
  18. Spectrochim. Acta v.44B no.739 Huang, M.;Hieftje, G. M.
  19. Spectrochim. Acta v.44B no.411 Nowak, M.;Van Der Mullen, J. A. M.;Van Lammeren, A. C. A. P.;Schram, D. C.
  20. Spectrochim. Acta v.41B no.133 Walters, P. E.;Gunter, W. H.;Zeeman, P. B.
  21. Spectrochim. Acta v.43B no.325 Walters, P. E.;Barnardt, C. A.
  22. J. Anal. At. Spectrom. v.12 no.281 Dubuisson. C.;Poussel, E.
  23. Appl. Spectrosc. v.51 no.68 Conver, T. S.;Yang, J.;Koropchak, J. A.;Shkolnik, G.;Rivera, C. F.
  24. Spectrochim. Acta Ivaldi, J. C.;Tyson, J. F.
  25. J. Anal. At. Spectrom. v.12 no.897 Brenner, I. B.;Zander, A.;Cole, M.;Wiseman, A.
  26. J. Anal. At. Spectrom. v.13 no.727 Todoli, J. L.;Mermet, J. M.
  27. J. Anal. At. Spectrom. v.12 no.198 Gagean, M.;Mermet, J. M.
  28. J. Anal. At. Spectrom. v.12 no.725 Skinner, C. D.;Salin, E. D.
  29. J. Anal. At. Spectrom. v.13 no.1265 Dubuisson, C.;Poussel, E.;Mermet, J. M.
  30. J. Anal. At. Spectrom. v.13 no.63 Dubuisson, C.;Poussel, E.;Mermet, J. M.;Todoli, J. L.
  31. J. Anal. At. Spectrom. v.12 no.349 Nakamura, Y.;Takahashi, K.;Kufirai, O.;Okochi, H.
  32. J. Anal. At. Spectrom. v.14 no.1807 Tian, X.;Emteborg, H.;Adams, F. C.
  33. J. Anal. At. Spectrom. v.14 no.1567 Tian, X.;Adams, F. C.

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