Bulletin of the Korean Chemical Society

  • 제22권4호
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  • Pages.409-412
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  • 2001
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Separation of Positional Isomers in a Calix[4]arene-methylsiloxane Polymer as Stationary Phase in Capillary GC

  • 발행 : 20010400
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초록

Poly(p-tert-butyltrimethoxymonopropyloxycalix[4]arene-methylsiloxane) (TBCX-MS) has been prepared and used as a stationary phase in isothermal capillary gas chromatographic separation of some positional isomers. Retention factors (k) and separatio n factors $(\alpha)$ for the isomers were measured and compared with those on poly(p-tert-butyl-dimethoxydipropyloxycalix[4]arene-tetramethyldisiloxane) (TBCX-TMDS), poly(dimethoxydipropyloxycalix[4]arenetetramethyl-disiloxane) (CX-TMDS). Most of the isomers investigated are well resolved on TBCX-MS. Retention of all the compounds decreases on the three phases in the order, TBCX-TMDS ${\geq}$ TBCX-MS > CX-TMDS. Similar retention values on TBCX-TMDS and TBCX-MS seem to indicate that retention property of the two phases is not significantly affected by the spatial position of the calixarene moiety.

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피인용 문헌

  1. Calixarenes as Stationary Phases in High Performance Liquid Chromatography vol.37, pp.3, 2001, https://doi.org/10.1080/10408340701244672
  2. Ionic Imprinted Calix[4]resorcinarene Host for Pb(II) Adsorbent Using Diallylaminomethyl-Calix[4]resorcinarene Copolymer vol.42, pp.10, 2001, https://doi.org/10.1246/cl.130427