Bulletin of the Korean Chemical Society

  • 제22권2호
  • /
  • Pages.183-188
  • /
  • 2001
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Synthesis and Properties of Poly(2-ethynyl-N-propargylpyridinium bromide)

  • 발행 : 20010200
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Ionic conjugated polymer, poly(2-ethynyl-N-propargylpyridinium bromide), was prepared by the cyclopolymerization of 2-ethynyl-N-propargylpyridinium bromide on using various transition metal catalysts, or by thermal methods without adding catalyst. The polymerization of 2-ethynyl-N-propargylpyridinium bromide catalyzed by PdCl2 gave the resulting polymers in relatively high yields. The polymer structure was characterized by various instrumental methods to confirm the conjugated polymer backbone structure carrying cumulated pyridine moiety. The polymers prepared by PdCl2 in DMSO or m-cresol were completely soluble in DMF, DMSO, and formic acid. The inherent viscosities of the resulting polymers were in the range of 0.07-0.19 dL/g. Thermal properties of the polymers were also discussed.

키워드

참고문헌

  1. J. Am. Chem. Soc. v.83 Stille, J. K.;Frey, D. A.
  2. J. Chem. Soc. v.3160 Hubert, A. J.;Dale, J.
  3. J. Am. Chem. Soc. v.71 Butler, G. B.;Bunch, R. L.
  4. Acc. Chem. Res. v.15 Butler, G. B.
  5. Makromol. Chem. Rapid. Commun. v.4 Yokota, K.;Matsumura, M.;Yamaguchi, K.;Takada, Y.
  6. Cyclopolymerization and Cyclocopolymerization Bulter, G. B.
  7. Korea Polym. J. v.4 Do, C. H.;Joo, Y. T.;Bulter, G. B.
  8. J. Am. Chem. Soc. v.73 Bulter, G. B.;Ingley, F. L.
  9. U.S.Patent3,288,770 Bulter, G. B.
  10. Tappi v.51 Hoover, M. F.;Carr, H. E.
  11. Ger. Offen. 1,814,597 Hoover, M. F.
  12. U.S. Patent 4,299,898 Clingman, M. W.;Auclair, C. J.
  13. Appl. Chem. v.13 Clingman, A. L.;Parrish, J. R.;Stevenson, R. J.
  14. Aust. J. Chem. v.19 Weiss, D. E.;Bolto, B. A.;McNeill, R.;Macpherson, A. S.;Siudak, R.;Swinton, E. A.;Willis, D.
  15. Pure and Appl. Chem. v.45 Breslow, D. S.
  16. Makromol. Chem. v.182 Cykor, P.;Kruhler, J. I.;Rubner, M. F.
  17. Bull. Korean Chem. Soc. v.11 Gal, Y. S.;Choi, S. K.
  18. J. Appl. Polym. Sci. v.42 Gal, Y. S.;Jung, B,;Choi, S. K.
  19. J. Appl. Polym. Sci. v.50 Gal, Y. S.;Choi, S. K.
  20. Prog. Polym. Sci. v.20 Toshima, N.;Hara, S.
  21. Chem. Rev. v.97 Roncali, J.
  22. Bull. Korean Chem. Soc. v.19 Chang. S. H.;Kang, S. K.;Jang, K. H.;Ryu, K. S.
  23. Synth. Met. v.71 Koda, T.;Ishiguro, A.;Kaneta, N.;Kishida, H.;Tokura, Y.;Ishikawa, K.
  24. Appl. Phys. Lett. v.53 no.21 Kaino, T.;Kubodera, K.;Kobayashi, H.;Kurihara, T.;Saito, S.;Tsutsuni, T.;Tokito, S.;Murata, H.
  25. Adv. mater. v.5 Nalwa, H. S.
  26. Polym. Bull. v.32 Lee, H. J.;Oh, J. M.;Choi, S. J.;Kim, H. K.;Choi, S. K.
  27. Science v.265 Samuel, D. W.;Ledoux, I.;Dhenaut, C.;Zyss, J.;Fox, H. H.;Schrock, R. R.;Silbey, R. J.
  28. Science v.265 Halvorson, C.;Hays, A.;Kraabel, B.;Wu, R.;Wudl, F.;Heeger, A. J.
  29. Synth Met. v.73 Lee, H. J.;Suh, M. C.;Shim, S. C.
  30. Macromolecules v.28 Lee, H. J.;Kang, S. J.;Kim, H. K.;Cho, H. N.;Park, J. T.;Choi, S. K.
  31. J. Polym. Sci. Polym. Chem. Ed. v.34 Lee, H. J.;Won, Y. H.;Kang, S. J.;Choi, S. K.;Kim, H. K.
  32. Synth. Met. v.71 Okawa, H.;Kurosawa, K.;Wada, T.;Sasabe, H.
  33. Macromol. Symp. v.118 Choi, S. K.;Lee, J. H.;Kim, H. K.
  34. Synth. Met. v.69 Akagi, K.;Goto, H.;Kadokura, Y.;Shirakawa, H.;Oh, S. Y.;Araya, K.
  35. Acta Polymer v.48 Pu, L.
  36. Bull. Korean Chem. Soc. v.18 Joo, K. S.;Kim, S. Y.;Chin, C. S.
  37. J. Polym. Sci. Polym. Shem.(Ed.) v.38 Jeon, S. J.;Shim, S. C.;Cho, C. S.;Kim, T. J.;Gal, Y. S.
  38. Bull. Korean Chem. Soc. v.21 Jeon, S. J.;Shim, S. C.;Cho, C. S.;Kim, T. J.;Gal, Y. S.
  39. Chem. Rev. v.100 Buchmeiser, M. R.
  40. Chem. Rev. v.100 Choi, S. K.;Gal, Y. S.;Jin, S. H.;Kim, H. K.
  41. Korea Polym. J. v.8 Kim, B. S.;Chen, L.;Gong, J. P.;Osada, Y.
  42. Macromolecules v.26 Kang, K. L.;Kim, S. H.;Cho, H. N.;Choi, K. Y.;Choi, S. K.
  43. Synth. Met. v.69 Gal, Y. S.;Jung, B.;Lee, W. C.;Choi, S. K.
  44. Eur. Polymer J. v.31 Gal, Y. S.;Choi, S. K.
  45. Macromolecules v.30 Choi, D. C.;Kim, S. H.;Lee, J. H.;Cho, H. N .;Choi, S. K.
  46. Polymer v.12 Gal, Y. S.;Cho, H. N .;Kwon, S. K.;Choi, S. K.
  47. Bull. Korean Chem. Soc. v.15 Gal, Y. S.;Jung, B.;Lee, W. C.;Choi, S. K.
  48. Bull. Korean Chem. Soc. v.19 Gal, Y. S.;Lee, W. C.;Lee, J. H.;Choi, S. K.
  49. New Pathway for Organic Synthesis Colguhoun, H. M.;Holton, J.;Thompson, D. J.;Twigg, M. V.
  50. Macromol. Reports v.A31 Gal, Y. S.
  51. J. Chem. Soc. Chem. Commun. v.327 Gal, Y. S.
  52. Acc. Chem. Res. v.17 Masuda, T.;Higashimura, T.

피인용 문헌

  1. Polymerization of 4-Dimethylamino-N-propargylpyridinium Bromide by Transition Metal Catalysts vol.40, pp.4, 2001, https://doi.org/10.1081/ma-120019067
  2. Synthesis and electro-optical properties of an ionic conjugated polymer: Poly[N-(6-azidohexyl)-2-ethynylpyridinium iodide] vol.7, pp.5, 2007, https://doi.org/10.1016/j.cap.2006.10.009
  3. Ionic Polyacetylene with Aromatic Functional Groups: Synthesis and Properties vol.209, pp.17, 2008, https://doi.org/10.1002/macp.200800284
  4. Electro-Optical and Electrochemical Properties of Poly(2-ethynyl-N-glycidylpyridinium bromide) vol.513, pp.1, 2001, https://doi.org/10.1080/15421400903217413
  5. Synthesis and characterization of an ionic conjugated polymer: Poly[2-ethynyl-N-(2-thiophenecarbonyl) pyridinium chloride] vol.47, pp.22, 2001, https://doi.org/10.1002/pola.23658
  6. Synthesis of an ionic polyacetylene derivative via phosphorus oxychloride-activated polymerization of 2-ethynylpyridine vol.644, pp.1, 2017, https://doi.org/10.1080/15421406.2016.1277493