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Comparison of the Sulfur Dioxide Primary Standard Gases of NPL and KRISS


Abstract

Comparison of sulfur dioxide primary standard gases of the Korea Research Institute of Standards and Science (KRISS, Korea) and the National Physical Laboratory (NPL, UK) was performed. 100 ${\times}$10-6 mol/mol and 1,000 ${\times}$10-6 mol /mol primary standard gases (designated NPL S115 and S114, respectively) prepared gravimetrically and validated in NPL were used as transfer standards. Transfer standards were analyzed by NDIR sulfur dioxide analyzer and compared with KRISS PSM 112-03-624 and PSM 112-03-625 prepared gravimetrically. Adsorption corrected relative deviations of the primary standard gases were agreed to within 0.1%, and this agreement is within the expanded uncertainties (k = 2) of the primary standards at the two laboratories.

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References

  1. Atmos. Environ. v.32 Kasper, A.;Puxbaum, H.
  2. J. Atmos. Sci. v.56 Heidam, N. Z.;Wahlin, P.;Christensen, J. H.
  3. Environmental Chemistry, (6 ed.) Manahan, S. E.
  4. Air Liquid Gas Encyclopaedia
  5. Reference Method for the Determination of Sulfur Dioxide in the Atmosphere U.S. Environmental Protection Agency
  6. ASTM D2914-95 Standard Test Methods for Sulfur Dioxide Content of the Atmosphere American Society for Testing and Materials
  7. JIS B 7952 Continuous Analyzers for Sulfur Dioxide in Ambient Air Japanese Standards Association
  8. Mutual Recognition of National Measurement Standards and of Calibration and Measurement Certificates Issued by National Metrology Institutes
  9. ISO 6142 Gas Analysis-Preparation of Calibration Gas Mixtures-Weighing Methods International Organization for Standardization
  10. Guide to the Expression of Uncertainty in Measurement International Organization for Standardization
  11. Metrologia v.37 Alink, A.
  12. Metrologia v.37 Alink, A.;van der Veen, A. M. H.