The study on Cr-C alloy electroplating and its characteristics

Cr-C합금 도금층 제조 및 특성 연구

  • 김동수 (한국기계연구원 표면기술연구부) ;
  • 김만 (한국기계연구원 표면기술연구부) ;
  • 박상언 (한국기계연구원 표면기술연구부) ;
  • 남기석 (한국기계연구원 표면기술연구부) ;
  • 장도연 (한국기계연구원 표면기술연구부) ;
  • 권식철 (한국기계연구원 표면기술연구부) ;
  • 신동수 (창원대학교 화학과)
  • Published : 2001.02.01

Abstract

The addition of organic compound containing -COOH, X$800_2$, -CHO group such as formic acid, formamide, formaldehyde or diethyleneamine to a chromium electroplating bath results in a chromium deposit in which carbon is incorporated. Such deposits have fewer defects than chromium layers produced by a conventional method. It was found that the as-deposited layers were amorphous and auger electron spectroscopy (AES) showed that carbon is distributed uniformly in the deposit. During heat treatment, Cr-C deposits began to crystallize at $400^{\circ}C$, and at $800^{\circ}C$ they were crystallized into chromium carbides and oxides. The effects of current density, amount of additives, applied current waveform on Cr-C alloy electroplating were examined.

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