Effects of Pores on the Microstructure of Melt-Processed $YBa_2Cu_3O_{7-x}$ Oxides

용융공정으로 제조한 $YBa_2Cu_3O_{7-x}$ 산화물의 미세조직에 미치는 기공의 영향

  • 김찬중 (한국원자력연구소 기능성재료연구) ;
  • 홍계원 (한국원자력연구소 기능성재료연구)
  • Published : 2001.06.01

Abstract

Formation of pores in melt-processed $YBa_2Cu_3O_{7-x}$ (123) oxides and its effect on the microstructure were studied. Spherical pores with a size of a few tens of microns were formed due to the evolution of oxygen gas during melting of a 123 oxide. Some of pores were converted into liquid pockets by liquid filling, but others remained unfilled. The liquid pockets were converted into spherical 123 regions with a lower $Y_2BaCuO_5$ (211)density through the peritectic reaction during subsequent cooling, while the pores were entrapped into the periteictically grown 123 grains. The spherical 123 regions often consists of a residual melt due to the unbalanced peritectically reaction.

Keywords

References

  1. Appl. Phys. Lett. v.52 S.Jin;T.H.Tiefel;R.C.Sherwood;M.E.Davis;R.B.van Dover;G.W.Kammlott;H.D.Keith
  2. Jpn. J. Appl. Phys. v.28 M.Murakami;M.Morita;K.Doi;K.Miyamoto
  3. Cryogenics v.30 M.Murakami;S.Gotoh;N.Koshizuka;S.Tanaka;T.Matsushita;S.Kambe;K.Kitazawa
  4. Mater. Lett. v.19 C.J.Kim;S.H.Lai;P.J.McGinn
  5. H. Mater. Res. v.10 C.J.Kim;H.G.Lee;K.B.Kim;G.W.Hong
  6. J. Am. Ceram. Soc. v.79 H.Y.Lee;C.J.Kim;G.W.Hong
  7. Metall. Trans. v.17A S.J.Cho;S.J.L.Kang;D.Y.Yoon
  8. J. Appl. Phys. v.35 D.R.Uhlmann;B.Chalmers;K.A.Jackson