Binder Removal by Supercritical $CO_2$ in Powder Injection Molded WC-Co

WC-Co계 분말사출성형에서 초임계$CO_2$에 의한 결합제 제거

  • 김용호 (한국과학기술연구원 초임계유체연구실) ;
  • 임종성 (한국과학기술연구원 초임계유체연구실) ;
  • 이윤우 (한국과학기술연구원 초임계유체연구실) ;
  • 김소나 (세라믹공정센터) ;
  • 박종구 (세라믹공정센터)
  • Published : 2001.06.01

Abstract

The conventional debinding process in metal injection molding is very long time-consuming and unfriendly environmental method. Especially, in such a case of injection molded parts from hard and fine metal powder, such as WC-Co, an extremely long period of time is necessary in the conventional slow binder removal process. On the other hand, supercritical debinding is thought to be the effective method which is appropriate to eliminate the aforementioned inconvenience in the prior art. The supercritical fluid has high diffusivity and density, it can penetrate quickly into the inside of the green metal bodies, and extract the binder. In this paper, super-critical debinding is compared with wicking debinding process. Wax-based binder system is used in this study. The binder removal rate in supercritical $CO_2$ have been measured at $65^{\circ}C$, 75$^{\circ}C$ in the pressure range from 20 MPa to 28 MPa. Pores and cracks in silver bodies after sintering were observed using SEM When the super-critical $CO_2$ debinding was carried out at 75$^{\circ}C$, almost all the wax (about 70 wt% of binder) was removed in 2 hours under 28 MPa and 2.5 hours under 25 MPa.

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References

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