Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
권호 표지

Resistance to Chemicals and Water of Epoxy Resin Cured with Phosphazene Derivatives

포스파젠 유도체에 의해 경화된 에폭시수지의 내수.내약품성

  • 윤흥수 (경일대학교 공과대학 섬유패션학과) ;
  • 최경식 (경일대학교 공과대학 섬유패션학과)
  • Published : 2001.06.01
Download PDF
⟨ Previous Next ⟩

Abstract

1, 1-diamino-3, 3, 5, 5-tetrachlorocyclotriphosphazene, 1, 1-diami-no3, 3, 5, 5-tetra-(p-bromophenoxy)cyclotriphosphazene, and 1, 1-diamino-3, 3, 5, 5-tetra-(p-chlorophenoxy) cyclotri-phosphazene(ACPP) was prepared from hexachlorocyclotriphosphazene and used for the curing agent of bisphenol A type epoxy resin and phenol novolak. The resistance to chemicals and water of the cured epoxy resins were examined by DMTA and compared with those of the epoxy rosins cured with phosphazene derivatives and 4, 4'-diaminodiphenylmethane. The effect of the curing agent on resistance to chemicals and water of the cured epoxy resins were investigated. The epoxy resins cured with 1, 1-diamino-3, 3, 5, 5-tetrachlorocyclotriphosphazene and 1, 1- diamino-3, 3, 5, 5-tetra- (p-bromophenoxy)cyclotriphosphazene showed superior resistance to chemicals and water to those of 1, 1-diamino-3, 3, 5, 5-tetra- (p-chlorophenoxy)cyclotriphosphazene and 4, 4'-diaminodiphenylmethane. It is an effective curing agent for epoxy resins to enhance the resistance to chemicals, water and tome proofing.

Keywords

References

  1. J. Polym. Sci. v.35 no.3 Part A: Polym. Chem Y. L. Liu
  2. J. Polym. Sci. v.35 no.1 S. R. Jong
  3. Polymer Communications v.29 A. L. Mukundan; K. Balasubramanian; K. S. V. Srinivasan
  4. プラスチックス v.38 no.1 唐川安弘;喜多晋三
  5. 强化プラスチックス v.33 no.4 小也常夫
  6. J. Appl. polym. Sci. v.39 Y. Nakamira; M. Yamaguchi; A. Kitayama
  7. 昭晃堂 ェポキツ樹脂 垣內弘
  8. Reinforced Plastic v.36 no.5 H. S. Yoon; N. Ishikawa; K. Takahashi
  9. J. Soc, Materials Sci. v.39 no.442 K. Takahashi; N. Ishikawa; H. S. Yoon
  10. Kobunshi Ronbunshu v.47 no.9 K. Takahashi; N. Ishikawa; H. S. Yoon; Kobunshi Ronbunshu
  11. Kobunshi Ronbunshu v.47 no.9 K. Takahashi; N. Ishikawa; T. Komori; H. S. Yoon
  12. J. Korean Fiber Soc. v.27 no.11 H. S. Yoon; S. I. Mah; Y. M. Won; K. Takahashi; N. Ishikawa; M. Kajiwara
  13. J. Soc, Materials Sci. v.37 no.421 K. Takahashi; T. yamamoto; M. Kajiwara
  14. J. Korean Fiber Soc. v.28 no.4 H. S. Yoon; S. I. Mah; Y. M. Won; M. W. Huh; K. Takahashi; N. Ishikawa; M. Kajiwara
  15. J. Soc, Materials Sci. v.40 no.451 K. Takahashi; N. Ishikawa; T. Kohno; H. S. Yoon
  16. J. Korean Fiber Soc. v.33 no.7 H. S. Yoon; K. S. Choi; K. Takahashi
  17. J. Korean Fiber Sco. v.36 no.7 H. S. Yoon
  18. J. Korean Soc. of Dyes and Finishers v.11 no.6 H. S. Yoon
  19. J. Chem. Sci.,(A),Inorg, Phys. Theor. M. V. Lenton; B. Lewis
  20. J. Inorg. nucl. Chem v.29 G. R. Feistel; T. Moeller
  21. Inorg. Chem v.5 E. T. McBee; K. Okuhara; C. J. Moton.
  22. Polyhedron v.2 M. Kajiwara; Y. Kurachi; Polyhedron