The Study on Preparation Parameters of $TiO_2$Catalyst for Photodecomposition of Ethanol as a VOC

VOC물질중 에탄올 광분해반응을 위한 $TiO_2$촉매의 제초변수 고찰

  • 이병용 (경희대학교 산학협력기술연구원 화학공학과) ;
  • 김성욱 (경희대학교 산학협력기술연구원 화학공학과) ;
  • 정석진 (경희대학교 산학협력기술연구원 화학공학과)
  • Published : 2001.08.01

Abstract

In this study, TiO$_2$, the popular photocatalyst, was used to decompose ethanol. TiO$_2$was prepared by the sol -gel method and coated on pyrex stick. A 15W, UV-A lamp was used as the UV light source and il gas chromatography (HP 5890) was used to confirm the concentrations of ethanol, $CO_2$and the intermediates. Variation of preparation parameters and calcination temperature for TiO$_2$photocatalysts in the sol -gel method caused changes of ethanol decomposition activity. The best ethanol photodecomposition activity was obtained on the sample when prepared with 0.14 mol of HCI, a mol of ethanol and 1.3 mol of TTIP ware mixed in sol-gel process and calcinated at 50$0^{\circ}C$ for 3 hours. Acetaldehyde was detected as an intermediate and decomposed to carbon dioxide and water at the end of the reaction.

Keywords

References

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