Effect of $MnO_2$ Addition on the Electric Properties in Pb($Mg_{1/3}Nb_{2/3}$)$O_3$ Relaxor Ferroelectrics

$MnO_2$ 첨가에 따른 Pb($Mg_{1/3}Nb_{2/3}$)$O_3$계 완화형 강유전체에서의 전기적 물성변화

  • 박재환 (한국과학기술연구원 재료공학부)
  • Published : 2001.07.01

Abstract

The effects of MnO$_2$ addition on the properties in Pb(Mg$_{1}$3/Nb$_{2}$3/)O$_3$ relaxor ferroelectrics were studied in the phase transition temperature range from -4$0^{\circ}C$ to 11$0^{\circ}C$. Specimens were made via solid state processing method. Dielectric properties, piezoelctric properties, electric-field-induced strain were examined to clarify the effect of MnO$_2$ addition in 0.9MN-0.1PT. As the amount of MnO$_2$ increases, the maximum dielectric constant and the dielectric loss decreases. Q$_{m}$ increased by increasing the doping contents of Mn. When 0.5wt% MnO$_2$ was doped, Q$_{m}$ increased from 95 to 480. The electric-filed-induced strain and polarization decreases as the amount of MnO$_2$ increases. From the experimental results, it was suggested that Mn behaves as an ferroelectric domain pinning element.ent.

Keywords

References

  1. Am. Ceram. Soc. Bull. v.65 no.4 Electrostrictive Actuators: Materials and Applications K. Uchino
  2. 전기전자재료학회지 v.10 no.1 Ba 치환된 $Pb(Mg_{1/3}Nb_{2/3})O_3$ -PvTiO₃-PbZrO₃계 세라믹스의 압전 및 변위특성에 관한 연구 지승한;이덕출;이능헌
  3. 전기전자재료학회지 v.6 no.2 $Pb(Mg_{1/2}Nb_{1/2})O_3-Pb(Fe_{2/3}W_{1/3})O_3-Pb(Mg_{1/3}Nb_{2/3})O_3$ 세라믹의 유전특성 박인길;류기원;이성갑;이영희
  4. J. Am. Ceram. Soc. v.74 smart Electroceramics R. E. Newnham;G. R. Ruschau
  5. J. Am. Ceram. Soc. v.74 no.5 Formation of the Perovskite Phase in the $Pb[Mg_{1/3}Nb_{2/3}]O_3$ -PbTiO₃System O. Bouquin;M. Lejeune;J. P. Boilot
  6. J. Appl. Phys. v.31 no.9B Effects of Manganese Addition on Piezoelectric Properties of $Pb(Zr_{0.5}Ti_{0.5})O_3$ T. kamiya;T. Susuki;T. Tsurumi
  7. 전기전자재료학회지 v.1 no.2 Pb(Zr,Ti)O₃-Pb(Mg,Nb)O₃에 MnO2 첨가가 전기적 성질에 미치는 영향 김현재;조봉희;정형진;박창엽
  8. 61 IRE 14 v.49 no.7 IRE Standard on Piezoelectric Crystals : Measurement of Piezoelectric Ceramics IRE
  9. J. Am. Ceram. Soc. v.67 no.5 Dielectric Properties of Lead-Magnesium Niobate Ceramics S. L. Swartz;T. R. Shrout;W. A. Schulze;L. E. Cross