Journal of Photoscience

Korean Society of Photoscience (한국광과학회)
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Photoreduction of Methyl Orange Catalyzed by Nile Red-Adsorbed $TiO_2$/Y Zeolites using Visible Light

  • Lee, Jeong-Jin (Department of Chemistry, Chungnam National University) ;
  • Kim, Yanghee (Department of Chemistry, Chungnam National University) ;
  • Minjoong Yoon (Department of Chemistry, Chungnam National University)
  • Published : 2001.03.01
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Abstract

Photoreduction of Methyl Orange Catalyzed by Nile Red-Adsorbed TiO$_2$/Y zeolites. Nile Red was successfully adsorbed on TiO$_2$/Y zeolites and the absorption profile is very broad with maxima, ca. 630 nm. The peak is largely red-shifted compared to that observed in hydrocarbon solvents. Furthermore, a broad and largely Stokes shifted emission band as observed around 660 nm. The largely Stokes shifted emission band should be originated from the excited state structural changes. In order to understand the photocatalytic activities of Nile Red-adsorbed TiO$_2$/Y zeolite, the photoreduction of Methyl Orange(5.0$\times$10$^{-5}$ M) was studied using visible light beyond 320 nm. Methyl Orange was effectively reduced by Nile Red-adsorbed TiO$_2$/Y zeolite, indicating the photocatalytic activity of Nile Red-adsorbed TiO$_2$ zeolites was enhanced by about eight times higher than that of TiO$_2$/Y zeolite.

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