환경위생공학 (Journal of environmental and Sanitary engineering)

대한환경위생공학회 (Korean Society for Environmental Sanitary Engineers)
권호 표지

N-Methylthiobenzyl-Chitosan Bead의 합성과 금속이온의 선택적 흡착능력

Synthesis of N-Methylthiobenzyl-Chitosan Beads and It's Selective Adsorption Abilities of Metal Ions

  • 최한영 (서울보건대학교 환경보건학과) ;
  • 한상문 (이화여자대학교 약학과) ;
  • 안병제 (동국대학교 화학과) ;
  • 이성호 (서울보건대학교 환경보건학과) ;
  • 유국현 (계명대학교 환경학부) ;
  • 이승진 (이화여자대학교 약학과)
  • 발행 : 2001.06.01
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Cross linked chitosan beads showed high selective adsorption abilities in order of $Au^{3+}$ > $Hg^{2+}$ > $Cu^{2+}$ > $Cd^{2+}$ > $Pt^{4+}$ > ${UO_2}^{2+}$ ions in mixed solution of various metal ions at pH 4.5. N-methyltyiobenzylated chitosan beads(MTB-chitosan beads) were prepared treating with p-(methylthio) benzaldehyde after cross linking of chitosan beads to give them a high selectivity in adsorption of metal ions. The MTB-chitosan beads demonstrated their selectivity on precious metals among various metal ions distinctively. Particularly, the MTB-chitosan had a peculiar selective adsorption on $Pd^{2+}$, $Au^{2+}$, and $Hg^{2+}$ions whilst the cross linked chitosan beads showed its high adsorption on $Pd^{2+}$ at pH 1.1. On the other hand, the cross linked chitosan beads showed its superiority in selective adsorption on $Au^{2+}$, $Cu^{2+}$, and $Hg^{2+}$ions to the MTB-chitosan at pH 4.5 of the test solution. Thus metal selectivities were given to chitosan beads through chemical modifications.

키워드

참고문헌

  1. Environ. Sci. Tech. v.29 Mechanism of formation and destruction of polychlorinated dibenzo-p-dioxins and dibenzofurans in heterogeneous system Rund, A.;Kees, O.
  2. Environ. Sci. Tech. v.30 Reactions of dibenzofuran and 1,2,3,4,7,8-hexachlorodibenzo-p-dioxin on municipal waste incinerator fly ash. Ruud, A.;Mischa, A.;Kees, O.;Harrie, A.J. Govers
  3. Environ. Sci. Tech. v.28 Mechanism of formation of poly- chlorinated dibenzo-p-dioxins and dibenzofurans in the catalyed combustion of carbon. Ronald, L.;Dennis, M.A.;Piter, S.;Kees, O.;Freek, K.
  4. Environ. Sci. Tech. v.28 Role of combustion and sorbent parameters in prevention of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans formation during waste combustion Brlan, K.G.;Paul, M.L.
  5. Pharmacol. Toxicol. v.69 2,3,7,8-Tetrachlorodibenzo-p-dioxin(TCDD) and related compounds as antiestrogens ; characterization and mechanism of action Safe, S.;Asstroff, B.;Zacharewski, T.;Dikerson, R.;Romkes, M.;Biegel, L.
  6. Toxicol. Appl. Pharamacol. v.114 In Utreo and lactational exposure of male rete to 2,3,7,8-Tetrachl-orodibenzo-p-dioxin. 2. Effects on sexual behavior and the regulation of luteininzing hormone secretion in adulthood Mably, T.;Moore, R.W.;Goy, R.W.;Peterson, R.E.
  7. Proceedings from the 4th International Conference on chitinand chitosan Lysozyme susceptibility and substitution site by chemical modification. Chitin and Chitosan Sashiwa, H.;Uraki, Y.;Saimoto, H.;Shigemasa, Y.;Tokura, S.;Skja-brek G.;Anthonsen T.;Sandford P.(ed.)
  8. Carbohydrate Polymer v.13 Carboxy-methyl-chitin as a drug carrer of sustained release. Tokura, S.;Baba, S.;Uraki, Y.;Miura, Y.;Nishi, N.;Hasegawa, O.
  9. Vaccine v.2 Immunological activity of chitin and its derivatives Nishimura, L.;Nishimura, S.;Nishi, N.;Saiki, I.;Tokura, S.;Azuma I.
  10. Int. J. Biol. Macromol. v.16 Enzymatic degradation of chitin and partially deacetylated chitin Shigemasa, Y.;Saito, K.;Sahiwa, H.;Saimoto, H.
  11. J. Bioactive and Compatible v.7 Applications and properties of chitosan Li, Q.;Dunn, E.T.;Grandmaison, E.W.;Goosen, M.F.A.
  12. Macromolecules v.17 A new polymerph of chitosan Qgawa, K.;Hirano, S.;Miyanishi, T.;Yui, T.;Watanabe, t.
  13. J. Bio. Sci. v.7 Hackman, R.;H., Auster
  14. Int. J. Biol. Macromol. v.2 Miya, M.;Iwamoto, R.;Yoshikawa, S.;Mima S.
  15. POLYMER v.19 Sannan, T.;Kurita, K.;Ogura, K.;Iwakura, Y.
  16. Journal of American Chemical Society v.85 no.22 Person, R.G.
  17. Wat. Res. v.4 Deans, J.R.;Dixon, B.G.