Evaluation and improvement of the stabilization process of the MSW Incinerator fly ash into cement

시멘트를 이용한 소각비산회의 안정화공정에 따른 문제점과 해결방안

  • 배해룡 (경주대학교 건설환경시스템 공학부)
  • Published : 2001.06.01

Abstract

This study was initiated to evaluate and resolve the potential problems caused as the MSWI(Municipal Solid Waste Incinerator) fly ash were stabilized and solidified into the cement. The physical and chemical properties of fly ashes (K and M) used in this study were fixed according to the operating conditions of the incineration plant. The compressible strength of the solidified matrix used in this study were measured at 7, 28, and 56 curing days, respectively, to evaluate the stability of the solidified matrix, which were further analyzed by XRD and SEM. The experimental results obtained in this study showed that the relatively long hours of curing periods were needed to solidify the fly ash. The solidified matrix containing K ash had the high and excellent compressible strength of $200{\;}kg/\textrm{cm}^2$, after 56 curing days, but was not good enough in appearance. The analytical data by SEM confirmed that the alkaline Na and K, which are highly dissolved in water, were included in the fly ash and evenly distributed into the exterior surface of the solidified matrix. Whereas, the solidified matrix containing M ash never showed such a compressible strength as shown in the K ash due to the severe fracture, even as early as 7 curing days. Based on its XRD analysis, it appeared that both $C_2S$ and $C_3S$ highly related to the compressible strength were not crystallyzed into the solidified matrix. However, the compressible strength of the solidified and cemented M ash was remarkably improved by 100 times, after the alkalinity was washed out, which indicated that it is equivalent to 30 to 40g per one kg of fly ash.

Keywords

References

  1. 소각로 fly ash 재 사용을 위한 안정화, 고형화 기술개발 배해룡
  2. Stabilization/Solidification of waste : Environmental evaluation of the perspectives of Waelz slag utilization in construction material Bae, H.R.
  3. Report on INSAVALOR/POLDN France How to improve chemical and physical stability of Waelz slag to withstand long term exposure to weathering and leaching condition BAE, H.R.;MEHU, J.;BARNA, R.
  4. Proceeding of international conference, WASCON97 Assessment of chemical sensitivity of Waelz slag BAE, H.R.;MEHU, J.;MOSZKOWICZ, P.;BARNA, R.;Goumans, J.J.M.;Van Der Sloot. H.A.;Albers. th.G.(eds.)
  5. Proceeding of international conference, WASCON94 French qualification procedure for solidification processes MEHU, J.;MOSZKOWICZ, P.;BARNA, R.;PHILIPPE, P.;MAYEUX, V.(et);Goumans, J.J.M.;Van Der Sloot, H.A.;Albers, Th.G.(eds.)
  6. Chemical Fixation and Solidification of Hazardous Waste Conner, J.R.
  7. 폐기물관리법 환경부
  8. 전국지정폐기물 발생 및 처리현황('95) 환경부
  9. EPA/530/R-93/012 Technical Resource Document : Solidification/Stabilization and its Application to Waste Materials U.S. EPA
  10. 시멘트화학총론 쌍용양회공업(주)
  11. Proc. Symp. Chem. Cement Tokyo v.2 Hydration of Portland Cement Copeland, L.E.;Kantro, D.L.