Effect of Annealing Temperature on the Mechanical Properties of Poly(p-dioxanone) Monofilament

열처리 온도가 Poly(p-dioxanone) 모노필라멘트의 기계적 특성에 미치는 영향

  • 김학용 (전북대학교 섬유공학과(공업기술연구소)) ;
  • 이덕래 (전북대학교 섬유공학과(공업기술연구소)) ;
  • 이세철 (전북대학교 섬유공학과(공업기술연구소)) ;
  • 최선웅 (한남대학교 고분자학과)
  • Published : 2001.04.01

Abstract

In this work the effect of annealing temperature on the tensile, thermal, and dynamic mechanical properties of poly(p-dioxanone) monofilament were investigate. The tensile strength and tensile elongation at beak increased with annealing temperature at a fixed immersion time. At the in-vitro immersion time of 10 weeks, the tensile strength as zero for samples annealed below 6$0^{\circ}C$, but for the samples annealed above 7$0^{\circ}C$ th tensile strength of 35 MPa was obtained. The hat of fusion increased with annealing temperature. Three endothermic peaks (84$^{\circ}C$, 93$^{\circ}C$, and 106$^{\circ}C$) were observed for the control sample and the sample annealed at 5$0^{\circ}C$. The endothermic peak at 93$^{\circ}C$ disappeared at annealing temperature of above 6$0^{\circ}C$. In the case of the immersion time of longer than 6 weeks, all samples showed a single endothermic peak. The maximum endothermic peak of samples increased with the immersion time at a fixed annealing temperature. The maximum loss modulus at each in-vitro immersion time showed an increasing tendency as the annealing temperature increased.

Keywords

References

  1. Polymer Science Technolgy Biodegradable Polymers in Medicine and Surgery R.L.Kronenthal
  2. Handbook of Biodegradable Polymers A.J.Domb;J.Kost;D.M.Wiseman
  3. U.S. Patent, 4,052,988 N.Doddi;C.C.Versfelt;D.Wasserman
  4. U.S. Patent, 4,452,973 D.J.Casey;M.S.Roby
  5. U.S. Patent, 4,438,253 D.J.Casey;K.R.Huffman
  6. U.S. Patent, 5,007,923 R.S.Bezwada;H.D.Newman
  7. U.S. Patent, 5,225,520 J.Kennedy;D.S.Kaplan;R.R.Muth
  8. U.S. Patent, 5,314,989 J.Kennedy;D.S.Kaplan;R.R.Muth
  9. U.S. Patent, 5,322,925 R.R.Muth;N.Totakura;C.K.Liu
  10. U.S. Patent, 5,403,347 M.S.Roby;S.L.Bennett;C.K.Liu
  11. U.S. Patent, 5,431,679 S.L.Bennett;C.K.Liu
  12. U.S. Patent, 5,554,170 M.S.Roby;S.L.Bennett;C.K.Liu
  13. U.S. Patent, 5,522,841 M.S.Roby;S.L.Bennett;C.K.Liu
  14. U.S. Patent, 5,502,159 C.K.Liu;S.L.Bennett;J.Kennedy;D.S.Kaplan;R.R.Muth
  15. U.S. Patent, 5,618,313 M.S.Roby;D.S.Kaplan;C.K.Liu;S.L.Bennett
  16. U.S. Patent, 5,695,879 H.Goldmann;H.Hierlemann;E.Mueller;H.Planck
  17. U.S. Patent, 5,902,875 M.S.Roby;Y.Jiang
  18. Biomaterials v.16 R.S.Bezwada;D.D.Jamiolkowski
  19. Biomaterials v.11 A.Metz
  20. J. Biomed. Mater. Res. v.20 C.C.Chu;A.Browning
  21. J. Biomed. Mater. Res. v.16 C.C.Chu;N.D.Campbell
  22. J. Polym. Sci., Polym. Phys. Ed. v.10 E.G.Lovering;D.C.Wooden
  23. J. Appl. Phys. v.46 W.M.Prest;D.J.Luca
  24. J. Appl. Polym. Sci. v.20 D.G.Brady
  25. Sen-i Gakkashi v.44 N.Ogata;F.Yoshimura;T.Yanagawa;K.Yoshida
  26. Polymer v.8 H.E.Bair;R.Salovey;T.W.Huseby
  27. J. Polym. Sci., Polym. Phys. Ed. v.18 G.Groeninckx;H.Reynaers
  28. Kolloid Z. Z. Polymer v.216 M.Jaffe;B.W.Wunderlich
  29. Macromolecules v.21 Y.Lee;R.S.Porter
  30. Macromolecules v.16 P.B.Rim;J.P.Runt
  31. Seoul National University, Korea, Ph.D Thesis Mechanical Properties and Degradation Behaviour of the Polyglycolic acid Suture Materials H.Y.Kim
  32. Polym. Eng. Sci. v.28 C.Zhou;S.B.Clough
  33. 섬유물리학 김상용;장동호;최영엽