Fibers and Polymers
- Volume 2 Issue 1
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- Pages.135-139
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- 2001
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- 1229-9197(pISSN)
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- 1875-0052(eISSN)
Formation of Metal Complex in a Poly(hydroxamic acid) Resin Bead
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Lee, Taek-Seung
(Organic & Optoelectronic Materials Lab., Department of Textile Engineering Chungnam National University) ;
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Jeon, Dong-Won
(Department of Clothing and Textiles, Ewha Womans University) ;
- Kim, Jai-Kyeong (Electronic Materials and Devices Research Center, Korea Institute of Science and Technology, P.O. Box 131) ;
- Hong, Sung-Il (Department of Fiber and Polymer Science, Seoul National University)
- Published : 2001.03.01
Abstract
Poly(hydroxamic acid) resin beads were prepared and complexed with various metal ions. We used IR spectroscopy to investigate the structure of metal complex. It proved that the products formed by introduction of metal ions gave stable and colored complex. It was found that the resin bead as synthesized would be a good column packing material for continuous extraction. Energy dispersive spectroscopy was use to study the distribution of metal ions in the resin matrix. It could be tentatively concluded that adsorption and diffusion of metal ions in the chelating resins mainly depended on the loading of the resin matrix which indicated interacting sites with metal ions.
Keywords
- Chelating resin;
- Poly(hydroxamic acid);
- Column extraction;
- Metal-ligand complex;
- Energy dispersive spectrum