Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Spectrophotometric Investigation of Silver Complex Solution with Thiomicher's Ketone

  • Published : 20000700
Download PDF
⟨ Previous Next ⟩

Abstract

The reaction between silver (I) and thiomicher's ketone (TMK) was sensitive at pH 5 and 8 in the presence of non-ionic or anion surfactant. We studied the complex solution and determined the properties by beta-correction spectrophotometry, which included the complex ratio and the stability constant of the complex. The results showed that complex Ag(TMK)2 was formed in the presence of alkylphend ethoxylates (emulsifier OP) and Ag(TMK)2 was formed in the presence of sodium dodecyl benzene sulfonate (SDBS). Their real absorptivities are as follows: $\varepsilonAg(TMK)540$ = 5.23 ${\times}$ 10(4), $\varepsilonAg(TMK)2(555)$ = l.05 ${\times}$ 10(5) Lmol(-l)cm(-1) both at pH 5 and $\varepsilonAg(TMK)2(555)$ = 7,52 ${\times}$ 10(4)lmol(-1)cm(-1) at pH 8. The stability constant of complex Ag(TMK) was equal to 1.23 ${\times}$ 10(5) at pH 5 and that of Ag(TMK)2 8.29 ${\times}$ 10(9) at pH 5 and 1.15 ${\times}$ 10(11) at pH 8.

Keywords

References

  1. Anal. Chim. Acta v.182 Ohshita, K.
  2. Midrochim. Acat. v.1 Traim, P.
  3. Talanta v.11 Dagnall, R. M.;West, T. S.
  4. Anal. Chim. Acta. v.109 Koh, T.
  5. Fenxi Huaxue v.17 Sun, G. B.;Zhou, J. P.;Tong, S. Y.
  6. Talanta v.30 Wei, F. S.;Yin, F.
  7. Anal. Chim. Acta v.50 Likussar, W.
  8. Anal. Chem. v.40 El-Ghamry, M. T.
  9. Lihua Jianyan-Huaxue Fence v.25 Zhang, G. F.
  10. Talanta v.30 Gao, H. W.
  11. Ind. J. Chem. v.35A Gao, H. W.
  12. J. Am. Chem. Soc. v.63 Bent, H. E.
  13. Zhur. Neorg. Khim. v.1 Yatzimirsky, K. B.