Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Electrocatalytic Effects for the Reduction of Thionyl Chloride in $Li/SOCl_2$ Cell Containing Schiff Base Metal(II) Complexes

  • Published : 20000600
Download PDF
⟨ Previous Next ⟩

Abstract

Electrocatalytic effects for the reduction of thionyl chloride in $LiAICI_4/SOCl_2$ electrolyte solution containing Schiff base M(II) (M; Co and Fe) complexes are evaluated by determining kinetic parameters with cyclic voltammetry and chronoamperometry at a glassy carbon electrode. The charge transfer process during the reduction of thionyl chloride is affected by the concentration of the catalyst. The catalytic effects are demonstrated from both a shift of the reduction potential for the thionyl chloride toward a more positive direction and an increase in peak currents. Catalytic effects are larger in thionyl chloride solutions containing the binuclear [M(II) $_2$ (TSBP)] complex rather than mononuclear [M(II)(BSDT)] complexes. Significant improvements in the cell performance have been noted in terms of both thermodynamics and activation energy for the thionyl chloride reduction. The activation energy calculated from the Arrhenius plots is 4.5-5.9 kcal/mole at bare glassy carbon electrodes. The activation energy calculated for the catalyst containing solution is 3.3-4.9 kcalmole, depending on whether the temperature is lowered or rasied.

Keywords

References

  1. J. Electrochem. Soc. v.126 no.513 Schlaikjer, C. R.;Goedel, F.;Marincic, N.
  2. J. Electrochem. Soc. v.125 no.1574 Dey, A. N.;Bro, P.
  3. In Lithium Battery Technology;Venkata-setty, H. V.(Ed.);Proc. Electrochemical Society Salmon, D. J.;Adamczyk, M. E.;Hendricks, L.L;Abels, L. L.;Hall, J. C.
  4. J. Electrochem. Soc. v.129 no.1853 Istone, W. K.;Brodd, R. J.
  5. J. Electrochem. Soc. v.131 no.2467 Istone, W. K.;Brodd, R. J.
  6. J. Electrochem. Soc. v.131 no.2471 Madou, M. J.;Szpak, S.
  7. J. Electrochem. Soc. v.134 no.2794 Madou, M. J.;Smith, J. J.;Szpak, S.
  8. J. Power Sources v.24 no.253 Hill, A. J.;Hampson, N. A.
  9. J. Electrochem. Soc. v.136 no.2455 Mosier-Boss, P.A.;Szpak, V.;Smith, J. J.;Nowak, R. J.
  10. J. Power Sources v.26 no.427 Bagotsky, V. S.;Kazariniv, V. E.;Volfkovich, Yu. M.;Kanevsky, L. S.;Beketayeva, L. A.
  11. J. Electrochem. Soc. v.140 no.11 Choi, Y. K.;Kim, B. S.;Park, S. M.
  12. Bull. korean Chem. v.15 no.456 Kim, W. S.;choi, Y. K.;Chjo, K. H.
  13. Proc. 30th Power Sources Symp.;The Electrochem. Soc. Inc Doddapaneni, N.
  14. Proc. of the Symposium on the Chemis-try and Physics of Electrocatalysis;The Electrochem. Soc. Inc. Doddapaneni, N.
  15. Bull. Korean Chem. Soc. v.16 no.21 Choi, Y. K.;Chjo, K. H.;Park, J. H.
  16. Electrochem. Soc. v.142 no.4107 Choi, Y. K.;Chjo, K. H.;Park, S. M.;Doddapaneri, N.
  17. J. Phy. Chem. v.60 no.1270 Ueno, K.;Martell, A. E.
  18. Inorg. Chem. v.29 no.608 Bernsterin, P. A.;Lever, A. B.;
  19. Electrochemical Methods Bard, A..J.;Faulkner, L. R.

Cited by

  1. Electrocatalytic effects of thionyl chloride reduction by polymeric Schiff base transition metal(II) complexes vol.252, pp.1, 2003, https://doi.org/10.1016/s0926-860x(03)00414-9