Bulletin of the Korean Chemical Society

  • 제21권5호
  • /
  • Pages.493-496
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  • 2000
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Rotational Distribution of $CO_2$($00^00)after Collisions with Hot Atoms

  • 발행 : 20000500
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초록

By use of the rotational distribution expression previously derived based on the collisional time correlation function formalism, the rotational distributions of $CO_2$ vibrational ground state (00°0) after collisions with hot H, D, or Cl atom have been constructed. Energy and rotational quantum number parameters which can characterize the rotational distributions are also calculated and compared with those deduced from the experimental distribution. The results from this work would be very useful in predicting the rotational distributions in the lower J region for which experimental data are not available due to the interference from the ambient $CO_2$.

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참고문헌

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피인용 문헌

  1. Collision-Induced Intramolecular Energy Flow in Highly Excited Toluene vol.24, pp.8, 2000, https://doi.org/10.5012/bkcs.2003.24.8.1223