Bulletin of the Korean Chemical Society

  • 제21권1호
  • /
  • Pages.39-43
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  • 2000
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Molecular Networks via Coordination Polymerization. Synthesis and Characterization of 2-D Polymeric Cobalt(II) Compounds Containing 3,3'-Dipyridyl Ether Series

  • 발행 : 20000100
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초록

New coordination polymers of general form, $$[CoL_2X_2]_n$$ (L = 3,3'-oxybis(pyridine) (obp), 1,4-bis(3-pyri-doxy) benzene (bpob); X = Cl, NCS), have been prepared via a slow diffusion method. The reaction of the present linkers with cobalt(II) ion affords infinite 2-dimensional sheet products. For $[Co(obp) $_2Cl_2]_n$$, the local geometry of the cobalt center is an octahedral arrangement with four nitrogen donors and two chlorine ions in trans positions. $$[Co(bpob)_2(NCS)_2]_n$$ has provided a similar structure: the local geometry of the cobalt atom is an octahedral arrangement with four pyridine units and two NCS groups in transpositions. The obp and bpob linkers connect two cobalt(II) ions defining the edges of 40- and 60-membered $[Co(II)]_4$ ring, respectively. Thermal analyses of the coordination polymers show significant thermal behavior associated with the characteristic structures.

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  1. Bond angle of isothiocyanate. Molecular network of cobalt(II) isothiocyanate with bis(3-pyridyl)dialkylsilanes vol.691, pp.1, 2004, https://doi.org/10.1016/j.molstruc.2003.12.009
  2. An Interpenetrating Diamonoid Coordination Polymer of Ag(I) with Bis(3-pyridoxy)benzene in Aqueous Media vol.27, pp.1, 2000, https://doi.org/10.5012/bkcs.2006.27.1.137
  3. Cobalt thiocyanate reagent revisited for cocaine identification on TLC vol.35, pp.7, 2011, https://doi.org/10.1039/c1nj20234k