Anisotropy in Gum and Black Filled SBR and NR Vulcanizates Due to Large Deformation

  • Park, Byung-Ho (Kumho Research and Department Center) ;
  • G.R. Hamed (Maurice Morton Institute of Polymer Science, College of Polymer Science and Polymer Engineering, The University of Akron)
  • 발행 : 2000.12.01

초록

After imposing a large pre-strain, anisotropy increases with increasing residual extension ratio. Gums have very low residual extension ratio and exhibit little anisotropy, while black filled SBR and especially sulfur-cured carbon black filled NR have large set and anisotropy. For carbon black filled rubber, samples subjected to tensile loading in perpendicular to the pre-strain direction have the same stress-strain curves shape as the sample without pre-strain (=isotropic samples), but slightly lower modulus. However, compared to isotropic or perpendicular directional samples to pre-strain direction, samples subjected to tensile loading in parallel to the pre-strain direction show low stress at low deformation, but have high stiffness at high deformation. Normalized anisotropy changes with strain. The normalized anisotropy for various deformations is a linear function of residual extension ratio.

키워드

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