A Semi-Interpenetrating Network for Temperature-Sensitive Polymer System

  • Yuk, Soon-Hong (Department of Polymer Science and Engineering, Han Nam University) ;
  • Cho, Sun-Hang (Advanced Materials Division, Korea Research Institute of Chemical Technology)
  • Published : 2000.04.01

Abstract

A semi-interpenetrating network (IPN) was prepared for a temperature-sensitive polymer system composed of sodium alginate and poly (N, N-dimethylaminoethyl methacrylate (DMAEMA)-co-ethyl acrylamide (EAAm)). The role of sodium alginate is to provide crosslinked network and that of poly(DMAEMA-co-EAAm) is to provide temperature responsiveness to the polymer system. Semi-IPN gel shows temperature-induced swelling transition at the same temperature of the lower critical solution temperature of poly(DMAEMA-co-EAAm) and its swelling kinetics is manipulated by the control of crosslinking densitv.

Keywords

References

  1. Macromolocules v.30 no.6856 S. H. Yuk;S. H. Cho;S. H. Lee
  2. European Polymer Journal v.35 no.1841 S. H. Cho;M. S. Jhon;S. H. Yuk
  3. Macromolocules v.21 no.3254 R. A. Siegel;B. A. Firestone
  4. macromolecules v.18 no.83 J. Ricka;T. Tanaka
  5. J. Macromol. Sci. Chem. v.A2 no.8 M. Heskins;J. E. Guillet
  6. J. Contr. Rel. v.4 no.213 A. S. Hoffman;A. Afrassiabi;L. C. Dong
  7. J. Contr. Rel. v.4 no.223 L. C.Dong;A. S. Hoffman
  8. Makromol. Chem., Rapid Commun. v.8 no.481 Y. H. Bae;T. Okano;S. W. Kim
  9. Macromol. Chem., Rapid Commun. v.9 no.185 Y. H. Bae;T. Okano;S. W. Kim
  10. Polymer v.29 no.731 C. L. McCormick;T. Nonaka;C. B. Johnson
  11. Pharm. Res. v.8 no.341 K. K. Kwok;M. J. Groves;D. J. Burgess
  12. Macromolecules v.25 no.5528 H. Feil;Y. H. Bae;J. Feijen;S. W. Kim
  13. Science v.269 no.525 Z. Hu;X. Zhang;Y. Li