Preparation of Linear Complex Compound with 1,2-Bis(4-pyridyl)ethane

1,2-비스(4-피리딜)에탄을 이용한 직선형 착화합물의 구축

  • 권윤정 (건국대학교 공과대학 섬유공학과)
  • Published : 2000.08.01

Abstract

Molecular-based materials with such functions as catalysis, magnetism and coordinate clathrations of one-, two-, and three-dimensional infinite frameworks have been extensively studied. Although rigid bridged ligands were frequently employed to construct these materials, flexible ligands were exploited less for this purpose. A one-dimensional polymer ${[Cd_2(=mu-bpe)_2](\mu-bpe)}(NO_3)_4}_n$ is prepared ; its structure is strikingly characterized by heptacoordinate Cd ions as well as by a unique main framework.

Keywords

References

  1. J. Am. Chem. Soc. v.116 M. Brookhart;M. I. Wagner
  2. Science v.261 H. O. Stumpf;L. Ouahab;Y. Pei;D. Gradjean;O. Kahn
  3. J. Am. Chem. Soc. v.120 S. Watanabe;O. Onogawa;K. Yoshida
  4. J. Am. Chem. Soc. v.116 K. Inoue;H. Iwamura
  5. J. Kor. Chem. Soc. v.39 M. H. Lee;W. W. Jeung;H. Y. Kim;I. W. Kim
  6. J. Kor. Chem. Soc. v.39 D. Y. Kim;N. J. Kin;B. S. Son;M. K. Doh
  7. J. Am. Chem. Soc. v.70 F. Basolo
  8. Inorg. Chem. v.6 D. A. Buckingham;P. A. Marzill;A. M. Sargeson
  9. J. Chem. Soc. Dalton Trans. S. Kitagawa;S. Matsuyama;M. Munakata;T. Emori
  10. Chem. Lett. S. Kitagawa;M. Munakata;T. Tanimura
  11. J. Appl. Phys. H. Tanino;K. Takahashi;T. Yao
  12. J. Am. Chem. Soc. v.113 B. J. Liu;R. Robson
  13. J. Am. Chem. Soc. v.114 S. B. Copp;S. Subramanianm;M. J. Zaworotko
  14. J. Chem. Soc., Chem. Commun. K. M. Park;T. Iwamoto
  15. Tetrahedron Lett. v.33 V. Ramamurthy;D. Sandetson
  16. J. Chem. Soc., Chem. Commun. B. Choudary;P. Bharathi
  17. J. Am. Chem. Soc. v.111 B. F. Hoskins;R. Robson
  18. J. Am. Chem. Soc. v.113 B. F. Abrahams;B. F. Hoskins;J. Liu;R. Robson
  19. J. Am. Chem. Soc. v.115 B. F. Abrahams;B. F. Hoskinslli;H. Alper
  20. J. Am. Chem. Soc. v.111 B. Hoskins;R. Robson
  21. J. Am. Chem. Soc. v.113 B. Hoskins;J. Liu;R. Robson
  22. Angew. Chem, Int. Ed, Engl. v.32 P. Behrens;G. Stucky
  23. Angew. Chem, Int. Ed, Engl v.27 J. Thomas
  24. Angew. Chem, Int. Ed, Engl. v.28 B. Choudary;G. Sharma;P. Bharathi