Effect of Sinter Additives on Sol-Gel Derived Alumina Fibres

  • Lakshmi, N.S. (Department of Physics, Ethiraj College for Women) ;
  • Gnanam, F.D. (Center for Ceramic Technology, Anna University)
  • Published : 2000.06.01

Abstract

Alumina fibre has been synthesized successfully by sol-gel technique. Boehmite sol was prepared by hydrolyzing aluminium iso-propoxide and peptizing it with nitric acid. The stable sol thus obtained was used for fibre drawing when their viscosity reached the required value as a result of progress of the hydrolyzation and polycondensation reaction. The fibres dried at 11$0^{\circ}C$ for 12 hours were sintered at 1$600^{\circ}C$ for 5 hours. A reasonable sintered density with better microstructure and strength have been attained using 2 wt% of urea, magnesia and silica as sinter additives. Thermal analysis with sintering additives of 2 wt% and phase determination of the heat treated fibres using XRD and FT IR spectra confirms the phase transitions. The observation of surface and cross-section of the fibres were made using SEM. Fibres of uniform circular cross-section is obtained by fixing the shape in a setting solution.

Keywords

References

  1. Handbook of Composites,Strong Fibres v.1 Alumina Fibres Preparation Properties and Application J.D.Birchall;J.A.A.Bradbury;J.Dinwoodie;W.Watt(Ed.);B.V.Perov(Ed.)
  2. J.Mat.Sci.Lett. v.5 Preparation of Porous Alumina Fibres by Unidirectional Freezing of Gel T.Maki;S.Sakka
  3. J.Non-cryst.Solids v.82 Formation of Alumina Fibres by Unidirectional Freezing of Gel T.Maki;S.Sakka
  4. J.Non-cryst.Solids v.100 Preparation of Alumina Fibers by Sol-gel Method T.Maki;S.Sakka
  5. Br.Ceram.Trans. v.98 Synthesis of Sol-gel Derived Alumina Powder: Effect of Milling and Calcination Temperature on Sintering Behavior M.Sathiyakumar;F.D.Gnanam
  6. J.Non Cryst.Solids v.48 The Sol-gel Transition in the Hydrolysis of Metal Alkoxide in Relation to tthe Formation of Glass Fibers and Films S.Sakka;K.Kamiya
  7. Am.Ceram.Soc.Bull. v.64 Sol-gel Synthesis of Glass Present and Future S.Sakka
  8. J.Mater.Sci.Lett. v.4 Thermal Stability of Aluminjum Oxide Prepared from Gel R.K.Dwivedi;G.Gowda
  9. J.Mater.Sci. v.22 Structural Evolution in Alumina Gel V.Sarawati;G.V.N.Rao;G.V.Ramarao
  10. J.Sol-gel Science and Technology v.9 Sol-gel Derived Tio₂-SiO₂Fibres B.G.Muralidharan;D.C.Agrawal