Processing of $Si_3N_4/SiC$ and Boron-Modified Nanocomposites Via Ceramic Precursor Route

  • Lee, Hyung-Bock (Department of Inorganic Material Engineering, Myong Ji University) ;
  • Rajiv S. Mishra (Department of Chemical Engineering & Materials Science University of California Davis) ;
  • Matt J. Gasch (Department of Chemical Engineering & Materials Science University of California Davis) ;
  • Han, Young-Hwan (Department of Chemical Engineering & Materials Science University of California Davis) ;
  • Amiya K. Mukherjee (Department of Chemical Engineering & Materials Science University of California Davis)
  • 발행 : 2000.09.01

초록

Consolidation of amorphous powders is emerging as a route for synthesis of high strength composite materials. Diffusion processes necessary for consolidation are expected to be more rapid in amorphous state(SRO) than in the crystalline state(LRO). A new synthesis technique of exploiting polymeric ceramic precursors(polysilazane and polyborosilazane) is derived for Si$_3$N$_4$/SiC and boron-modified nanocomposites for extremely high temperature applications up to 200$0^{\circ}C$. The characterization methods include thermal analysis of DTA, and XRD, NMR, TEM, after pyrolysis, as a function of time and temperature.

키워드

참고문헌

  1. J.Wiley & Sons,New York Ultrastructure Processing of Ceramics and Composites, D.Seyferth;G.H.Wiseman,L.L.Hench;D.R.Ulrich
  2. Eng.Chem.Process.Des.Dev v.23 B.G.Penn,F.E.Ledbetter Ⅲ;J.M.Clemons,Ind
  3. Ceram.Bull v.62 R.R.Wills,R.A.Markle;S.P.Mukherjee,
  4. J.Mater.Sci v.30 O.Funayama,H.Nakhara,M.Okoda,M.Okumura;T.Isoda
  5. Chem.Mater v.5 K.Su.E.E.Remsen,G.A.Zank;L.G.Sneddon
  6. J.Am.Ceram.Soc, v.73 D.Seyferth;H.Plenio,
  7. J.Eur.Ceram,Soc v.5 R.Riedel,M.Seher;G.Becker,
  8. J.Lipowitz and R.S.Reaoch,Am.Ceram.Soc.Bull v.66 G.E.Legrow,T.F.Lim.
  9. J.Am.Ceram.Soc v.72 G.T.Burns;G.Chandra,
  10. U.S.Patent4,550,151 Organoborosilicon Polymer and a Method for the Preparation Thereof M.Takamizawa,T.Kobayashi,A.Hayashida;T.Takeda
  11. H.Schonfelder;R.J.Brook Nature v.355 R.Riedel,G.Passing,
  12. H.Schonfelder;F.Aldinger,Nature v.374 R.Riedel,H.J.Kleebe,
  13. Mat.Res.Soc.Symp.Proc v.286 K.Niihara,K.,A.Nakahira;T.Sekino,S.Komarneni,J.C.Parker;G.J.Thomas,
  14. J.Bill,Mater.Sci.Lett v.15 J.Seitz;
  15. J.Mater.Sci v.24 Y.D.Blum,K.B.Schwartz;R.M.Laine
  16. in Chemical Processing of Advanced Materials H.R.Alcock,Ed.L.L.Hench;J.K.
  17. Z.Metallkd v.87 J.Bill;F.Aldinger,
  18. Adv.Mater v.7 J.Bill;F.Aldinger