Effects of Additives on the Characteristics and Microstructure of $UO_2$ Pellet

$UO_2$ 소결체의 특성 및 미세구조에 미치는 첨가제의 영향

  • Published : 2000.07.01

Abstract

Effect of various kinds of additive such as AlOOH, Al(OH)3, Al2Si2O5(OH)4, Nb2O5, TiO2 and MgO on the properties and microstructures of UO2 pellet has been examined. All the tested dopants had played a role to reduce sintered density and open porosity. It was revealed that the addition of TiO2 made pellet more stable thermally. UO2 pellet doped with 0.2wt% TiO2 was swelled rather than densified after annealing for 24 hrs at 1$700^{\circ}C$. It was attributed to large pore with spherical shape. Titinia and silicon coexisted with Al element were more effective to increase grain size than other additives. It could be also revealed that the formation of liquid phase was the main cause of grain growth.

Keywords

References

  1. Nucl. Technol. v.26 The Influence of Fuel Microstructure on In-Pile Densification W. Chubb;A. C. Hott
  2. J. Kor. Nucl. Soc. v.26 Microstructure Development during Sintering of ? Doped UO₂Pellets under H₂and CO₂Atmospheres K. W. Song
  3. J. Nucl. Mater. v.18 Characteristics of UO₂Powder and Pellets for LWR Fuel I. Amato;R. L. Colomb;A. P. Balzari
  4. J. Nucl. Mater. v.52 The effect of Titania on Grain Growth and Densification on Sintered UO₂ J. B. Ainscough;F. Rigby;S. C. Osborn
  5. Proc. on Fission Product Behavior in Ceramic Oxide Fuel v.17 B. E. Ingleby;K. Hand
  6. KWU Report U6 v.U6 Reduction in Open Porosity of UO₂by Microdoping with Aluminum G. Gradel
  7. J. Am. Ceram. Soc. v.51 Grain Growth in UO₂-Al₂O₃in the Presence of a Liquid Phase K. W. Lay
  8. J. Nucl. Mater. v.116 UO₂Fuel Pellet Microstructure Modification through Impurity Additions K. C. Radford;J. M. Pope
  9. Ceramic Processing and Sintering M. N. Rahaman