한국대기환경학회지 (Journal of Korean Society for Atmospheric Environment)

  • 제16권3호
  • /
  • Pages.265-275
  • /
  • 2000
  • /
  • 1598-7132(pISSN)
  • /
  • 2383-5346(eISSN)
한국대기환경학회 (Korean Society for Atmospheric Environment)
권호 표지

열탈착/GC/FID를 이용한 B, T, X 분석의 정확도 및 정밀도 평가

A Study on Evaluation of Accuracy and Precision on B, T, X Analysis Using Thermal Desorption/Gas Chromatograph/Flams Ionization Detector

  • 박정근 (한국산업안전공단 산업안전보건연구원) ;
  • 유기호 (한국산업안전공단 산업안전보건연구원)
  • 발행 : 2000.06.01
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

By using thermal desorption/gas chromatograph/flame ionization detector(TD/GC/FID), this study was carried out to evalute an accuracy and a precision on Benzene(B), Toluene(T), o-Xylene(X) analysis in an industrial hygiene laboratory. Limits of detection of TD/GC/FID on B, T, X were showed 13.75ng/sample or less. For the accuracy of the method by concentration levels, overall bias was showed 7.7% as an absolute value, and the pooled coefficient of variation showed 3.51%. For the precision on repeatability of peak area and retention time between within-run and between-run of analytical system, it is showed the results of within-run gave better than those of between-run. Also the accuracy by sorbents(Tenax TA and Chromosorb 106)was evaluated, and the precision on reproducibility between MDHS72 and this study was compared. It is showed it is possible for TD/GC/FID to evaluate accurately B, T, X concentration levels of less than 1ppm at indoor or outdoor of workplaces in Korea.

키워드

참고문헌

  1. 한국산업위생학회지 v.5 no.1 활성탄관에 포집된 극성유기용제의 탈착효율에 관한 연구 김경란;백남원
  2. 여천공단 작업환경 특별조사 용역 최종보고서 석유화학사업장의 옥외환경에 대한 노출평가 김광종;김정철;오인성
  3. 고시 제97-65호 화학물질 및 물리적인자의 노촐기준 노동부
  4. 공단지역 작업환경 평가에 관한 연구 노재훈;원종욱;김치년;송재석;전미령;박윤정;황철;왕승준;이상희;김용래
  5. 여천공단 근로자 건강관리 및 작업환경 실태조사,종합보고서 문영환
  6. 안전보건 v.10 no.10 열탈착법을 이영한 유기용제 측정분석의 고찰 박정근
  7. 작업환경측정 및 평가(1판) 백남원;박동욱;윤충식
  8. 한국대기보전학회 측정분과회 기술강습회 대기중 VOC 측정에 있어서 QC/QA의 중요성 백성옥
  9. 한국산업위생학회지 v.7 no.1 활성탄관에 포집된 극성 및 비극성 유기용재 분석시 탈착용매 종류에 따른 탈착효율 비교 손연주;김현욱
  10. 산업보건연구원 연구보고 총람 v.6 작업환경 측정방법의 적정화 연구-측정대상 확대 및 측정횟수 방법의 개선을 중심으로 오세민;박정근
  11. 환경부 연구용역과제 '96 화학물질 유통실태조사 이은
  12. 기기분석개론 최재성
  13. 한국대기보전학회 측정분석분과회 워크샵 환경 대기중 VOC의 포집과 분석 허귀석
  14. Method TO-17(2nd edition) Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air by Woolfenden, E.A. and McClenny, W. A. Environmental Protection Agency
  15. Methods for the Determination of Hazardous Substances (MDHS) MDHS 72 (Volatile Organic Compounds in Air), Laboratory Method Using Pumped Solid Sorbent Tubes, Thermal Desorption and Gas Chromatography Health and Safety Executive
  16. Am. Ind. Hyg. J. v.50 no.1 Thermal Desorption Efficiencies of Two-Component Organic Solvents from Activated Carbon Hori, H.;I. Tanaka;T. Akiyama
  17. ISO 5725-1, PartⅠ: General Principles and Definitions Accuracy (Trueness and Precision) of Measurement Methods and Results International Organization for Standardization
  18. ISO 3534-1, PartⅠ: Probability and General Statistical Terms Statistics-Vocabulary and Symbols International Organization for Standardization
  19. Guidelines for Sampling and Analytical Methods Development and Evaluation no.95-117 National Institute for Occupational Safety and Health;Kennedy, E.R.;T.J. Fischbach;R. Song;P.M. Eller;S.A. Shulman
  20. Method No. 1501(4th ed.) NIOSH Manual of Analytical Methods National Institute for Occupational Safety and Health
  21. Method No. 2549(4th ed.) NIOSH Manual of Analytical Methods National Institute for Occupational Safety and Health
  22. OSHA Analytical Methods Nanual(2nd ed.) Method Evaluation Guidelines of the Organic Methods Evaluation Branch Occupational Safety and Health Administration
  23. ATD400 User's Nanual Perkin Elmer
  24. Documentation of the NIOSH Validation Tests Taylor, D.G.;R.E. Kupel;J.M. Bryant
  25. J. Air Waste Mana. Assoc. v.47 Monitoring VOCs in Air Using Pumped Sampling onto Sorbent Tubes Followed by Thermal Desorption-capillary GC Analysis: Summary of Reported Data and Practical Guidelines for Successful Application Woolfenden, E.A.
  26. Instrumental Methods Quality Assurance in Environmental Monitoring Woolfenden, E.A.