Pretreatment Effect of Waste Automotive Catalysts for VOCs Combustion

VOCs 연소를 위한 자동차 폐촉매의 전처리 효과

  • 문정선 (여수대학교 건설환경공학부)
  • Published : 2000.04.01

Abstract

For a characterization of the pretreated waste automotive catalyst the following analysis techniques were applied : EA(Elemental Analysis) BET(Brunaure-Emmett-Teller) and ICP-AES(Inductively Coupled Plasma-Atomic Emission Spectrometry). The combustion activity of waste automotive catalyst was investigated for methanol acetaldehyde and toluene as model VOCs in a fixed bed reactor. carbon deposit amount was decreased with increasing catalyst showed a good catalytic activity for VOCs combustion at 40$0^{\circ}C$. Catalytic activity for methanol acetaldehyde and toluence combustion was very excellent and decreased with mileage. The catalytic activity of a waste automotive catalyst for methanol combustion increased after acid treatment. The acid effect of catalytic activity was summarized as follows: HNO3>HCI>H2SO4>CH3COOH. The waste automotive catalyst regenerated by the pretreatment method might have a excellent catalytic activity for VOCs combustion.

Keywords

References

  1. 공업화학 전망 v.2 no.1 자동차 재활용 활성화를 위한 정책적/기술적 접근 김상욱;송영욱;이재영
  2. 한국공업화확학회지 v.10 no.4 백금족 금속과 규산염을 포함하는 모노리스형 자동차 폐초개의 ICP-AES분석을 위한 극초파단 분해 전처리 기법의 응용 김충현;우성일;전성환
  3. 대한금속학회지 v.6 no.4 자동차 폐촉매로부터 백금족 금속의 회수기술 현황 이재천
  4. 대기환경보전법 대기환경보전법
  5. 환경백서 (행정간행물 등록번호: 38000-67030-06-51) 환경백서 (행정간행물 등록번호: 38000-67030-06-51)
  6. Studies in Surface Science and Catalysis v.116 Causes of Deactivation and an Effort fo Regenerate a Commercial Spent Three-way Catalyst Angelidis, T. N.;M. M. Koutlemani;S. A. Sklavunos;Ch. B Lioutas;A. Voulgaropoulos;V. G. Papadakis;H. Emons
  7. Applied Catalysis A:General v.1 no.1 Methane Combustion over Palladium Catalysts - The Effect of Carbon Dioxide and Water on Activity Bruch, R.;F. J. Urbano;P. K. Loader
  8. Applied Industrial Catalysis v.25 Applied Industrial Catalysis Ellingham, R. E.;J. Garrett;G. E. Leach.(ed)
  9. J. Catal v.110 Controlled Atmosphere Electron Microscopy Study of the Gasification of Graphite by Water, Hydrogen and Oxygen Catalyzed by Nickel/Potassium Mixture Carrazza, J.;J. J. Chludzinski;H. Heinemann;G. A. Somorjai;T. K. Baker
  10. Precious Metals 1983 v.209 Precious Metals 1983 Musco, S. P.;D. A. Reese.(ed)
  11. EPA 749-F-94-013 Chemical in the Environment: Office of Pollution Prevention and Toxics(OPPT) Chemicl Fact Sheet