Growth of Vertically Aligned Carbon Nanotubes on Co-Ni Alloy Metal

Co-Ni 합금위에서 수직방향으로 정렬된 탄소나노튜브의 성장

  • Published : 2000.08.01

Abstract

We have grown vertically aligned carbon nanotubes in a large area of Co-Ni codeposited Si substrates by the thermal CVD usign $C_2H_2$ gas. Since the discovery of carbon nanotubes, growth of carbon nanotubes has been achieved by several methods such as laser vaporization, arc discharge, and pyrolysis. In particular, growth of vertically aligned nanotubes is important to flat panel display applications. Recently, vertically aligned carbon nanotubes have been grown on glass by PECVD. Aligned carbon nanotubes can be also grown on mesoporous silica and Fe patterned porous silicon using CVD. In this paper, we demonstrate that carbon nanotubes can be vertically aligned on catalyzed Si substrate when the domain density of catalytic particles reaches a certain value. We suggest that steric hindrance between nanotubes at an initial stage of the growth forces nanotubes to align vertically and each nonotubes are grown in bundle.

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References

  1. Iijirna, S. Helical microtubules of graphitic carbon. Nature (London) 354, 56-58 (1991) https://doi.org/10.1038/354056a0
  2. Journet C. et al. Large-scale production of single-walled carbon nanotubes by the electric-arc technique. Nature (London) 388, 756-758 (1997) https://doi.org/10.1038/41972
  3. Thess, A. et al. Crystalline ropes of metallic carbon nanotubes. Science 273, 483-487 (1996) https://doi.org/10.1126/science.273.5274.483
  4. Terrones, M. et al. Controlled production of aligned-nanotube bundled. Nature (London) 388, 52-55 (1997) https://doi.org/10.1038/40369
  5. Saito, Y. et al. Conical beams from open nanotubes. Nature (London) 389, 554-555 (1997) https://doi.org/10.1038/39221
  6. de Heer W. A. et al. A carbon nanotube field-emission electron source. Science 270, 1179-1180 (1995) https://doi.org/10.1126/science.270.5239.1179
  7. Collins.n P. G., Zettl, A. Unique characteristics of cold cathode carbon nanoyube matrix field emitters. Phys. Rev. B55, 9391-9399 (1997) https://doi.org/10.1103/PhysRevB.55.9391
  8. Wang, Q. H. et al. A nanotube-based field-emission flat panel display. Appl. Phys, Lett. 72, 2912-2913 (1998) https://doi.org/10.1063/1.121493
  9. Ren, Z. F. et al. Synthesis of large arrays of well-aligned carbon nanotubes on glass. Science 282, 1105-1107 (1998) https://doi.org/10.1126/science.282.5391.1105
  10. Li, W. Z. et al. Large-scale synthesis of aligned carbon nanotubes. Science 274, 1701-1703 (1996) https://doi.org/10.1126/science.283.5401.512
  11. Fan, S. et al. Self-oriented regular arrays of carbon nanotubes and their field emission properties. Science 283, 512-514 (1999) https://doi.org/10.1126/science.283.5401.512
  12. Kong, J. et al. Synthesis of individual single-walled carbon nanotubes on patterned silicon wafers. Nature (London) 395, 878-881 (1998) https://doi.org/10.1038/27632