Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis of 6,13-Bis(thymidinyl)-5,12-dioxocyclams and the Molecular Structure of the (R,S)-Isomer

  • Published : 1999.08.20
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Abstract

The three stereoisomers of the 6,13-bis(thymidinyl)dioxocyclam 6 were synthesized through photoreaction of the chromium alkoxycarbene complex 2 and 1-(benzyloxycarbonyl)-4,4-dimethyl-D 2 -imidazoline. The molecular structure of (R,S)-6 was elucidated by X-ray crystallography.

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References

  1. Chem. Rev. v.94 Busch D. H.;Alcock, N.
  2. J. J. Am. Chem. Soc. v.54 Wagler, T. R.;Fang, Y.;Burrows, C. J.
  3. J. Am. Chem. Soc. v.113 Nam, W.;Ho, R.;Valentine, J. S.
  4. Acc. Chem. Res. v.27 Burrow, C. J.;Rokita, S. E.
  5. Chem. Rev. v.94 Halcrow, M. A.;Christou, G.
  6. J. Org. Chem. v.62 Hsiao, Y.;Hegedus, L. S.
  7. J. Am. Chem. Soc. v.117 Dumas, S.;Lastra, E.;Hegedus, L. S.
  8. J. Org. Chem. v.59 Hegedus, L. S.;Moser, W. H.
  9. J. Am. Chem. Soc. v.114 Betschart, C.;Hegedus, L. S.
  10. J. Chem. Soc., Chem. Comm. Armaroli, N.;Barigelletti, F.;Cakigero, G.;Flamigni, L.;White, C. M.;Ward, M. D.
  11. Hydrogen Bonding in Biological Structures Jeffrey, G. A.;Seanger, W.
  12. Chem. Ber. v.100 Fischer, E. O.;Maasbol, A.
  13. J. Chem. Soc. A Connor, J. A.;Jones, E. M.
  14. Tetrahedron Lett. v.15 Ogilvie, K. K.;Thomson, E. A.;Quilliam, M. A.;Westmore, J. B.