Bulletin of the Korean Chemical Society

  • 제20권7호
  • /
  • Pages.801-804
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  • 1999
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Thermal and Photoinduced Silylallylation Reactions of Organic Halides with 3-Stannyl-2-(silylmethyl)propene

  • 발행 : 1999.07.20
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초록

Thermal and photoinduced silylallylation reactions of organic halides with 3-stannyl-2-(silylmethyl)propene are explored. Silylallylations occur in moderate to high yields, producing various functionalized allylsilane products in which halide carbon is bonded to the terminal alkenic carbon of allylsilane with the removal of tributyltin group. The reactions, which tolerate functional groups such as carbonyl, ester, nitrile, acetal, and ketal, hold synthetic potential for the construction of functionalized allylsilanes.

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참고문헌

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