Application of Composites Composed of Phosphoric Acid-Doped Silica Gel and Styrene-Ethylene-Butylene-Styrene Elastomer to Electric Double-Layer Capacitors

  • Matsuda, Atsunori (Department of Applied Materials Science, Graduate School of Engineering Osaka Prefecture University) ;
  • Honjo, Hiroshi (Department of Applied Materials Science, Graduate School of Engineering Osaka Prefecture University) ;
  • Hirata, Kazuki (Department of Applied Materials Science, Graduate School of Engineering Osaka Prefecture University) ;
  • Tatsumisago, Masahiro (Department of Applied Materials Science, Graduate School of Engineering Osaka Prefecture University) ;
  • Minami, Tsutomu (Department of Applied Materials Science, Graduate School of Engineering Osaka Prefecture University)
  • Published : 1999.12.01

Abstract

Highly proten-conductive elastic composites have been successfully prepared from $H_3PO_4$-doped silica gel and styrene-ethylene-butylene-styrene block elastic copolymer. In addition solid state electric double-layer capacitors have been fabricated using the composite as an electrolyte and activated carbon powders(ACP) hybridized with the composite as a polrizable electrode. The cyclic voltammogram of the electric double-layer capacitor fabricated demonstrated that electric charge was stored in the elecric double-layer at the interface between the polarizable electrode and the electrolyte. The value of capacitance of the capacitor was 10 F/(gram of total ACP), which was comparable to that of the capacitors using conventional liquid electrolytes.

Keywords

References

  1. J. Power Sources v.60 Capacitors: Operating Principles, Current Market and Technical Trends A. Nishino
  2. Carbon v.28 no.4 Acivated Carbon Fiber Sheets as Polarizable Electrodes of Electric Double Layer Capacitor I. Tanahashi;A. Yoshida;A. Nishino
  3. Carbon v.29 no.7 Characterization of Activated Carbon Fiber Cloths for Electric Double Layer Capacitor by Adsorption Method I. Tanahashi;A. Yoshida;A. Nishino
  4. Denki Kagaku v.48 no.1 An Electric Double-Layer Capacitor Using Organic Electrolyte S. Sekido;Y. Yoshino;T. Muranaka;M. Mori
  5. Bull. Chem. Soc. Japan v.63 no.12 Comparison of the Electrochemical Properties of Electric Double-Layer Capacitors with an Aqueous Electrolyte and with a Nonaqueous Electrolyte I. Tanahashi;A. Yoshida;A. Nishino
  6. J. Electrochem. Soc. v.137 no.10 Electrochemical Chracterization of Activated Carbon-Fiber Cloth Polarizable Electrodes for Electric Double-Layer Capacitor I. Tanahashi;A. Yoshida;A. Nishino
  7. Denko Kagaku v.61 no.4 Electric Double Layer Capacitor Using Sulfolane-Based Electrolytic Solution Y. Sanada;K. Hiratsuka;T. Morimoto;K. Kurihara
  8. J. Electrochem. Soc. v.140 New Electric Double-Layer Capacitors Using Polymer Solid Electrolytes Containing Tetraalkylammonium Salts Y. Matsuda;M. Morita;M. Ishikawa;M. Ihara
  9. J. Electrochem. Soc. v.141 no.7 Electric Double-Layer Capacitor Composed of Activated Carbon Fiber Cloth Eletrodes and Solid Polymer Electrolytes Containing Alkylammonium Salta M. Ishkawa;M. Morita;M. Ihara;Y. Matsuda
  10. J. Electrochem. Soc. v.143 no.12 All-Solid-State Electric Double-Layer Capacitor with Isotropic High-Density Graphite Electrode and Polyethylene Oxide/LiClo₄ Polymer Electrolyte X. Liu;T. Osaka
  11. Silica-Gel Ionics v.74 Proton-Conducting Silica-Gel Films Doped with a Variety of Electrolytes M. Tatsumisago;H. Honjo;Y. Sakai;T. Minami
  12. Silica-Gel Ionics v.113-115 Electric Double-Layer Capacitor Using HCIO₄-Doped Silica Gels as a Solid Electrolyte A. Matsuda;H. Honjo;M. Tatsumisago;T. Minami
  13. J. Sol-Gel Sci. Tech. Preparation and Characterization of Highly Proton-Conductive Composites Composed of Phosphoric Acid-Doped Silica Gel and Styrene-Ethylene-Butylene-Styrene Elastomer K. Hirata;A. Matsuda;H. Hirata;M. Tatsumisago;T. Minami
  14. J. Power Sources v.77 Electric Double-Layer Capacitor Using Composites Composed of Phosphric Acid-Doped Silica Gel and Styrene-Ethylene-Butylene-Styrene Elastomer as a Solid Electrolyte A. Matsuda;H. Honjo;K. Hirata;M. Tatsumisago;T. Minami
  15. Macromolecules v.21 no.2 Novel Polymer Electrolytes Based on ABA Block Copolymer F.M. Gray;J.R. MacCallum;C.A. Vincent;J.R.M. Giles