Ceramic Materials having Strain Sensing Properties -The CaO-NiO Ceramics-

  • Seo, Sato-Shi (Institute of Industrial Science, The University of Tokyo) ;
  • Akira Kishimoto (Institute of Industrial Science, The University of Tokyo) ;
  • ;
  • Published : 1999.06.01

Abstract

The strain sensing properties of th system xNiO-(1-x) CaO with various compositions (x=0.001-0.05) are evaluated and the origin of the phenomena is guessed. We have found out that the high temperature electrical conductivity of the xNiO-(1-x)CaO increases by applying the compressive stress at $1000^{\circ}C$. When the applied load is removed, the electrical conductivity rapidly decreases and returns to the original value, but a small hysteresis of the stress-conductivity curve is observed. After the loading test, the lattice parameter of the specimen is found lengthened. The correlation between the lengthening of the lattice parameter and the increases in the electrical conductivity by loading is discussed. The amount of the "expanded type" Ni(II)O6 clusters in the xNiO-(1-x)CaO grains is supposed to be increased by the applied stress, which would be the origin of the strain dependent electric conduction in the xNiO-(1-x)CaO system.aO system.

Keywords

References

  1. J. Am. Ceram. Soc. v.80 no.6 Strain Dependent Electrical Condcution in the System NiO-CaO Y. Nakamura;H. Ogawa;T. Nakashima;A. Kishimoto;H. Yanagida
  2. J. Am. Ceram. Soc. v.77 no.4 Prediction of Fracture and Detection of Fatigue in Ceramic Composites from Resistivity Mesurement A. Ishida;M. Miyayama;H. Yanagida
  3. Jpn. J. Appl. Phys. v.37 no.10A Effect of Moisture Absorption on Piezoresistance of Conducting Polymer Composite Thin Films S. Hirano;A. Kishimoto;M. Miyayama
  4. Introduction to Ceramics(2nd ed.) W. D. Kingery;H. K. Bowen;D. R. Uhlmann
  5. J. Am. Ceram. Soc. v.79 no.8 A Model to Compute Phase Diagrams in Oxides with Empirical or First Principles Energy Methods and Application to the Solbuility Limit in the CaO-MgO System P. D. Tepesch;A. F. Kohan;G. D. Garbylsky;G. Ceder;C. Coley;H. T. Stokes;L. L. Boyer;M. J. Mehl
  6. J. Phys. Soc., Jpn. v.25 no.6 Electronic Adsorption Spectrum of Ni²+ in CaO M. Igarashi;T. Sakurai
  7. J. Am. Ceram. Soc. v.52 no.8 The system NiO-CaO D. E. Smith;T. Y. Tien;L. H. Van Vlack
  8. PacRim, SXIIP-9-93P Characterization of CaO-NiO Solid Solution T. Nakashima;N. Motohira;Y. Nakamura;H. Yanagida