한국대기환경학회지 (Journal of Korean Society for Atmospheric Environment)

  • 제15권3호
  • /
  • Pages.327-333
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  • 1999
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  • 1598-7132(pISSN)
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  • 2383-5346(eISSN)
한국대기환경학회 (Korean Society for Atmospheric Environment)
권호 표지

모세관 전지영동법에 의한 굴뚝에서 포집된 NaOH 용액속의 염소이온의 측정

Determinaton of Chloride Ion Captured into Strong NaOH Solution from Chimney by Capillary Electrophoresis

  • 발행 : 1999.06.01
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초록

Determination of chloride ion in concentrated NaOH solution by capillary electrophoresis has been studied. The analysis was performed by indirect UV absorption detection using chromate buffer at 254nm. The matrix effect of the sample has been observed so that the sensitivity in strong NaOH solutaion has decreased up to 10% of that in distilled water. The pH effect of the sample on the sensitivity of CE peaks has been investigated. The method for increasing the sensitivity have been investigated and the optimum pH and concentration of the buffer were 7.5 and 10mM, respectively. A cationic surfactant cetyltrimethylammonium bromide(CTAB), was added to a buffer solution in order to reverse the electroosmotic flow(EOF) in the capillary. This results in a short analysis time and better peak shapes. Using this optimum condition, the determination of chloride ion in real environmental sample has been performed, which is captured in strong NaOH absorbent prepared for absorbing gas from chimney. The standard addition method has been applied for the quantitative analysis, and it was obtained the good reproducibility.

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참고문헌

  1. 환경산업총람 v.216 환경관리연구소
  2. 대기오염 소음 진동 공정시험 방법 v.213 등화기술 편집위원회
  3. J.of Chro v.A187 Analysis of difficult samples by capilary zone electrophoresis Ⅰ. Simultancous separation of detrimental anions in concrete digested with concentrated nitric acid Harakuwe,I.;P.R.Haddad;R.Thomas
  4. J.Chromatogr. v.602 no.241 Explosive residue analysis by capillary electrophoresis and ion chromatography Hargadon,K.A.;B.R.McCord
  5. Quantitative Chemical Analysis v.107 Hartis,D.C.
  6. Electrophoresis v.14 Capillary electrophoresis/mass specltometry deteimination of inorganic ions using and ion spray-sheath flow interface Huggins, T.G.;J.D. Henion
  7. Capillary Electrophoresis of Small moecules and Ions Jandik,P;Gunther Bonn
  8. Capillary Zone Electrophoresis Science v.222 no.266 Jorgenson,J.W.;K.D.Lukacs
  9. Anal. Sci. v.12 Sepaiation of Morpholinc, N-Mcthylmorpholinc and N-methy-Imorpholine-N-oxide by Indirect UV Absorption Capillary Electrophoresis Jung, G.Y.;T.H. Kim;H.B. Lim
  10. Analytical Science v.13 Simultancous Determinatin of Chromium (III) and Chromium (VI) on Aqueous Solution by Capillary electrophoresis with on-column UV-VIS detection Jung, G.Y.;Y.S. Kim;H.B. Lim
  11. Anal Chem. v.66 determination of Chloride, nitrate, Sulfale. Nitute Fluoride. and phosphatc by on line coupled capillary isotachophoresis-capillary zone electro-phoresis with conductivity detection Kaniansky, D.;J. Zelensky;A. Hybenova;F.I. Onuska
  12. J. of Chromatogia, A. v.654 Capillary electrophoretci analysis of inorganic cations Role of complexing agect and buffer pH Lin,T.I.;Y.H.Lee;Y.C.Chen
  13. J Chromatogi. v.625 Optimization of Indirect Photometric deteetion of anions in high-performance capillary electrophoresis Ma, Y.;R. Zhang
  14. Electrophoresis v.18 Analysis of morgame pollutants by capillary eletrophoreis Timerbaev,A.R.
  15. Anal Chem.Acta v.359 Capillary electrophoresis : The state-of-the-ait in metal speciation studies Zlotorzynska,E.D.;E.P.C.Lar;A.R. Timerbaev