Korean Journal of Crystallography (한국결정학회지)

Korean Crystallographic Association (한국결정학회)
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Crystal Structure of $[Ni(L)](ClO_4)_2$ (L: 2,13-bis(2-pyridylmethyl)-3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,$0^{1.18},0^{7.12}$]docosane)

$[Ni(L)](ClO_4)_2$(L: 2,13-bis(2-pyridylmethyl)-3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,$0^{1.18},0^{7.12}$docosane) 착물의 결정구조

  • Park, Ki-Young (Department of Chemistry, Mokwon University, Taejon) ;
  • Suh, Il-Hwan (Department of Physics, Chungnam National Uiversity, Taejon) ;
  • Kim, Jing-Gyu (Department of Physics, Chungnam National Uiversity, Taejon) ;
  • Park, Young-Soo (Department of Physics, Chungnam National Uiversity, Taejon)
  • Published : 1999.06.01
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Abstract

The complex [Ni(L)](ClO4)2 (1) (L=2,13-bis(2-pyridylmethyl)-3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,01.1807.12]docosane) has been synthesized and characterized by X-ray crystallography. (1) crystallizes in the triclinic, space group P, with a=10.948(2), b=10.948(2), c=14.911(4) , α=93.73(2), β=93.77(2), γ=99.29(2)o, V=1754.8(7) 3, Z=2, R1(wR2) for 5217 observed reflections of [I>2σ(I)] was 0.048(0.099). The coordination environment around nickel(II) ion shows a distorted octahedron with four secondary and tertially amines of the macrocycle and two nitrogen atoms of pyridylmethyl groups.

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