Economic and Environmental Geology (자원환경지질)

The Korean Society of Economic and Environmental Geology (대한자원환경지질학회)
권호 표지

Gas and Solute Compositions of Fluid Inclusions in Quartz from Some Base-metal ore Deposits, South Korea

남한의 주용 금속광상산 석영내의 유체포유물의 가스성분과 용존성분의 화학조성

  • 김규한 (이화여자대학교 과학교육과) ;
  • 정해란 (이화여자대학교 과학교육과)
  • Published : 1999.10.01
Download PDF
⟨ Previous Next ⟩

Abstract

Gas and chemical compositions of fluid inclusions in quartz some of Au-Ag, Pb-Zn-Cu and W-Mo mineral deposits in South Kores were analyzed to interpret the sources of ore fluid and the depositional condition of ore minerals in base-metal ore deposits. Fluid inclusions in quartz from the gold and silver mines are characterized by $CO_2$ rich fluids which have a wide range in $CH_4 \;and\; CO_2$ contents ($CH_4/CO_2$=0.001-0.225). The $CO_2$ rich but $CH_4$-poor nature of the fluid reflects the high fo2 condition during the mineral precipitation. The C2H6 is detected in hydrothermal quartz vines in metasedimentary rocks from the Jeonjoo-il, Youngbokari and Taechang mines. The $CH_4 /CO_2$ rations in W-Mo bearing quartz veins range from 0.005 to 0.214, which is similar with those in Au-Ag mines. However, skarn formation stage. Fluid inclusions, A relatively good correlation between Na and Cl contentrations reflects varible salinity in the fluid inclusion, it is suggested that the chemistry of promary magmatic hydrothermal fluids has changed during post-magmatic alteration and/or wall rock alteration processes. The content of gas compositions also depends on the kinds of country rocks, supporting above conclusion.

Keywords

References

  1. Am. Mineral. v.34 Release and analysis of gases from geological samples Andrawes, F.F.;Gibson, E.K.
  2. Soc. Mining Geol. (Japan Special Issue) v.8 Late stage processes of felsic magmatism Burnham, C.W.;Ohmoto, H.
  3. Eaplores geothermal systems in Geochemistry of hydrotehrmal ore deposits Ellis, A.J.;H.L. Barnes (ed.)
  4. Geochim. Cosmochim. Acta v.44 Geothermal gas equilibria Giggenbach, W.F.
  5. Geochim. Cosmochim. Acta v.59 Factores zffecting gas analysis of inclusion by quadrupole mass spectrometry Graney, J.R.;Kesler, S.E.
  6. Res. Rept. Ministry of Japan Fluid inclusions studies of ore deposits in south Korea: In : Granite provinces and associated ore depositsin South Korea Kaneda, H.;Shimazaki, H.;Lee, M.S.;Tsusue, A(ed.)
  7. Jour. Korean. Inst. Mining Geol v.15 no.3 Sulfer isotope composition and isotopic temperature of the Shinyemi leaded zinc ore depoits, western Taebaegsan metallogenic belt Kim, K.H.;Nakai, N.
  8. South Korea. Mining. Geol. v.38 no.6 Stable isotope studies of the Sangdong tungsten ore deposits Kim, K.H.;Kim, O.J.;Nakai, N.;Lee, H.J.
  9. Geochem. J. v.29 no.5 Oxigen and sulfer isotopic compositions of quatz, barite and sulfide minerals from the Sambo Pb-Zn-barite ore deposits, South Korea Kim, K.H.;Mizutani, Y.;Moon, H.S.
  10. Czech Geol. Suv. Chemical evolution of hydrothermal solutions during variscan and post0Veriscan minerlization in the Erzgebirge, Germany: In: Metallogency of collosional orogens Klemm, W.;Reimar Seltmann;Horst Kmpt;Peter Mller(Eds)
  11. Acta Geol. Pol v.28 Pneumatolytic and hydrothermal activity in the Karkonosze-Izerablock Kozlowski, A.
  12. J. Geochem. Explor. v.42 Analysis of fluid inclusion gas surverge for the assesment of lode deposits(with refernce to gold and tungston deposits) Lazar. B.;Holland, H.D.
  13. Mineralogical study on complex sulphide-sulphosalt ores from Jaggun mine Lee, H.K.
  14. Bull. Sci. Eng. Res. Lab. Waseda Univ. v.126 Study of the magnetiian skarn type magnetite deposit at the Shinyemi mine, Taebaegsan ore belt, Korea (1) Mariko, T.;Yang, D.Y.
  15. The genesis of the Sangdong tungsten deposits, the Republic of Korea Moon, K.J.
  16. Jour. Korean Inst. Mining Geol. v.26 Geochemistry of fluid inclusions of W. Cu and Au-Ag ore deposits in South Korea and its significance Moon, K.J.
  17. Reviews in Mineralogy v.16 Stable isotope geochemistry of ore deposits : In: Stab;e isotopes in high temperature geological processes Ohmoto, H.;Valley;Taylor;O'Neil(Eds.)
  18. Geol. Soc. Korea, Jour. v.17 no.3 A study of the genesis of the metallic oredeposits in Hwanggangri region Park, H.J.;Lee, S.M.;Kim, S.J.
  19. Geochim. Cosmochim. Acta v.59 Rb-Sr isotopic analysis of fluid inclusions in quartz: Evaluation of bulk extraction procedures and geochronometer systematics using synthetic fluid inclusions Pettke, T.;Diamond, L.W.
  20. Geochim. Cosmochm. Acta v.54 Fluid inclusion analysis-prologue and epilogue Roedder, E.
  21. Geochim. Cosmochim. Acta v.51 The ion pair contant and other thermodynamic properties of HCI up to 350°C Ruaya, J.R.;Seward, T.M.
  22. Geochim. Cosmochm. Acta v.60 An X-ray adsorption (EXAFS) spectroscopic study of aquated $Ag^{+}$ in hydrothermal solutions to 350℃ Seward, T.M.C.;Henderson, M.B.;Charnock, J.M.;Dobson, B.R.
  23. Econ. Geol. v.83 Gold rich mesothermal vein deposits of the Republic of Korea. Geochemical Studies of the jungwon gold area Sheleton, K.L.;So, C.S.;Chang, J.S.
  24. Mining Geol. v.33 no.4 K-Ar ages of the Jecheon granitic complex and related molybdenite deposits in South Korea Shibata, K.;Park, N.Y.;Uchiumi, S.;Ishihara, S.
  25. Geochem. J. v.19 Sulfur isotopic ratios of ore deposits associated with Mesozoic felsic magmatisms in South Korea, with special reference to gold-silver deposit Shimazaki, H.;Sakai, H.;Kaneda, H.;Lee, M.S.
  26. Mining Geol. v.36(4) Three epochs of gold minerlization in South Korea Shimazaki, H.;Lee, M.S.;Tsusue, A.;Kaneda, H.
  27. Mining. Geol. v.37 no.6 K-Ar ages of some W-Mo deposits and their bearing on metallogeny of South Korea Shimazaki, H.;Shibata, K.;Uchiumi, S.;Lee, M.S.;Kaneda, H.
  28. J. Phys. chem. v.54 Modeling of the thermodynamics of electrolyte solutions to high temperatures including ion association Simonson, J.M.;Holmes, H.F.;Busey, R.H.;Mesmer, R.E.;Archer, D.G.;Wood, R.H.
  29. Econ. Geol. v.87 Geochemistry and genesis of hydrothermal Au-Ag-Pb-Zn deposits in the Hwanggangri mineralized district, Republic of Korea So, C.S.;Yun, S.T.
  30. Econ. Geol. v.92 Jurassic mesothermal gold minerlization of the Samhawnghak mine, Youngdong area, republic of Korea: Constraints of hydrothermal fluid geochemistry So, C.S.;Yun, S.T.
  31. Econ. Geol. v.78 no.8 Carbon, hydrogen, oxigenad sulfur isotopeand fluid inclusion study of the Waolag tungsten-molybdnum depositsm Republic of Korea; Fluid histories of mrtalmorphic and ore forming events So, C.S.;Rye, D.M.;Shelton, K.L.
  32. Econ. Geol. v.82 Stable isotope and fluid inclusion studies of gold-silver bearing hydrothermal vein deposits, Cheonan-Cheongyang-Nonsan mining district, republic of Korea So, C.S.;Shlton, K.L.
  33. Mining Geol. v.39 no.1 Geochemical studies of hydrothermal gold-silver deposits, Republic of Korea; Youngdong mining district So, C.S.;Yun, S.T.;Choi, S.H.;Shelton, K.L.
  34. Jour. Min. Pet. Econ. Geol. v.83 Geochemical studies on Au-Ag hydrothermal vein deposits, Republic of Korea. Jinan-Jeongup minerlized area So, C.S.;Chi, S.J.;Choi, S.H.
  35. N. Jb. Miner. Abh. v.158 Stable isotope and fluid inclusions studies of goldsilver bearing vein deposits, Cheonan-Cheonyang-Nonsan mining district, Republic of Korea: Cheonan area So, C.S.;Chi, S.J.;Shelton, K.L.
  36. Econ. Geol. v.79 Geology anf geochemistry of the Sambo Pb-Zn deposits, Republic of Korea So, C.S.;Park. M.E.;Shelton, K.L.;Seidmann, D.E.
  37. Econ. Geol. v.78 The dae Wha tungstenmolybdnum mine, Republic of Korea: A Geochemical study So, C.S.;Shelton, K.L.;Seidmann, D.E.;Skinner, B.J.
  38. Jour. Min. Pet. Econ. Geol. v.88 no.2 hydrothermal W-Mo mineralization of the Cheongyang mine, Republic of Korea: A Fluid inclusion and stable isotope study So, C.S.;Yun, S.T.;Lee, J.H.
  39. Geochim. Cosmochim. Acta v.59 Resolving mantle and crustal contributions to ancient hydrothermal fluids: He-Ar isotopes in fluid inclusions from Dae hwa W-Mo mineralization, South korea Stuart, F.N.;Burnard, P.G.;Taylor, R.P.;Turner, G.
  40. Mining Geol v.36 no.6 Gold and silver ores from the Geumwang mine in South Korea and Their minerlization Sugaki, A.;Kim, O.J.;Kim. W.J.
  41. Distribution of carbon bearing gas species in plutonic rocks and their behaviors in igneous processes (Unpublished) Sugisaki, R.;Araki, M.;Nagamine, K.
  42. Can. J. Earth Sci. v.25 Methane and hydrogen in Mid-ocean ridge basalt glasses: Analysis by vacum crushing Welhan, J.A.
  43. Transactions of the Institution of Ming and Metallurgy v.105 Geochemical studies of W-Mo vein deposits in Susan area, Hwanggangri district, Korea; metal zoning related to progressive meteoric water mixing in a granitic hydrothermal system Yun, S.T.;So, C.S.;Youm, S.J.
  44. 광산지질 v.10 청양 충석광상의 지질과 유체포유물에의 한 온도 측정에 관한 연구 김규한
  45. 자원환경지질 v.29 no.4 경상 퇴적분지내에 분포하는 소위 마산암에 대한 암석성인 연구 김규한;이화정
  46. 자원환경지질 v.29 no.4 남한의 중생대 화강암 중의 가스성분과 유체포유물 연구 김규한;박성숙;杉崎隆一
  47. 자원환경지질 v.30 no.6 부평 은 광산 지역의 유문암질안과 화강암류의 가스 및 유체초유물연구 김규한;하우영
  48. 자원환경지질 v.28 no.2 싱동 중석-몰리브덴 광상의 광화관졍 상동 화강암의 Nd-Sr 동위원소비 및 가스성분 김규한;신유희
  49. 무극 금-은광상에 대한 유체포유물 및 안정동위원소 분석연구 v.23 no.1 김규한;김옥준;장원선
  50. 광산지질 v.20 no.3 만장 동광산에 대한 유체포유물 및 안정동위원소 분석연구 김규한;신정숙
  51. 지질학회지 v.16 no.2 한국의 일부 금속광상의 유황동우원소성분 및 동위원소 지질온도에 관한 연구 김규한;中井信之
  52. 광산지질 v.16 no.4 통영 금광상 성인과 유체포유물 박희인
  53. 광산지질 v.7 no.2 대화 중석-휘수연 광상산 광물의 유체포유물 연구 박희인;최석원
  54. 지질학회지 v.34 no.4 화강암중의 가스 화학조성: 국내 화강암류의 생성환경에 대한 응용 이민성;이종익;Kaneda, H.
  55. 광산지질 v.21 no.3 한국의 일부 금은광상에서 산출되는 금-은 광물과 광상의 생성조건 이현구;최진우
  56. 한국의 광상 no.10 대한광업진흥공사 (KMPC)
  57. 자원환경지질 v.28 no.6 한국중부와 동남부지역 금-은광화작용의 성인적 특성 최선규;최상훈
  58. 광산지질 v.21 no.4 충청북도 영동지역 근은광상의 금은 광화작용에 관한 연구 최선규;지세정;박성원
  59. The origin and evolution of fluids in magmatic-hydrothermal systems : In : Geochemistry of hydrothermal ore deposits Giggenbach, F.F.
  60. Mining Geol v.36 Compositional variations in Au-Ag series minerals from some gold deposits in the Korean peninsula Shikazono, N.;Shimizu, M.
  61. Schweitz. Miner. Petrogr. Mitt. v.75 He, Ar, U-Pb, and Rb-Sr isotopic systematics of fluid inclusions in qyartz and associated vein minerals and native gold from epigenetic late Alpine Auveins in NW Italy Pettke, T.;Diamond, L.W.;Frei, R.;Villa, I.M.