Synthesis of Photoconductive N-unsaturated Alkylcarbazole Derivatives

광전도성 N-불포화알킬카르바졸 유도체의 합성

  • Jung, Eun-Sil (Dept. of Materials Science & Engineering, DanKook University) ;
  • Cho, Eul-Hoon (Dept. of Materials Science & Engineering, DanKook University) ;
  • Chung, Pyung-Jin (Dept. of Materials Science & Engineering, DanKook University)
  • 정은실 (단국대학교 공학대학 재료공학과) ;
  • 조을훈 (단국대학교 공학대학 재료공학과) ;
  • 정평진 (단국대학교 공학대학 재료공학과)
  • Received : 1998.02.17
  • Accepted : 1998.05.18
  • Published : 1998.08.10

Abstract

The N-unsaturated alkylcarbazole derivatives were synthesized by the nucleophilic unimolucular substitution reaction ($S_N1$) of carbazole with unsaturated alkyl chloride. These reactions between carbazole and unsaturated alkyl chloride were conducted in dimethyl sulfoxide (DMSO) containing alkali (NaOH or KOH) at room temperature for 4 hrs under nitrogen atmosphere. The mole ratios of carbazole, alkali and unsaturated alkyl chloride were 1:6:1, respectively. All of the compounds of starting materials and reaction products were characterized by CHN analysis, $^1H$-NMR and FR-IR spectroscopy.

N-불포화알킬카르바졸유도체는 카르바졸과 염화불포화알킬과의 친핵적1분자 치환반응 ($S_N1$)에 의해서 합성했다. 이들의 반응은 질소분위기하상온에서 알칼리 (NaOH 또는 KOH)를 함유한 DMSO용매중 카르바졸과 염화불포화알킬을 4시간에 걸쳐 행했으며, 이때 카르바졸에 대한 알칼리와 염화불포화알킬과의 몰비는 1:6:1이었다. 반응물질과 반응생성물은 모두 CHN원소분석, $^1H$-NMR 및 FT-IR에 의하여 측정되었다.

Keywords

Acknowledgement

Supported by : 단국대학교

References

  1. Jpn. J. Appl. Phys. v.27 C. Adachi;S. Tokito;T. Tsutsui;S. Saito
  2. Appl. Phys. Lett. v.55 C. Adachi;S. Tokito;T. Tsutsui;S. Saito
  3. Appl. Phys. Lett. v.57 C. Adachi;S. Tokito;T. Tsutsui;S. Saito
  4. Chem. Lett. Y. Hamada;C. Adachi;T. Tsutsui;S. Saito;J. Kido;K. Nagai;Y. Ohashi
  5. Chem. Lett. J. Kido;K. Nagai;Y. Ohashi
  6. Jpn. J. Appl. Phys. v.31 J. Kido;K. Hongawa;M. Kohda;K. Nagai;K. Okuyama
  7. Appl. Phys. lett. v.61 J. Kido;M. Kohda;K. Nagai;K. Okuyama;K. Nagai
  8. Polym. Adv. Tech. v.3 J. Kido;Y. Guo;J. McBreen;K. Nagai;Y. Okamoto
  9. Phys. Rev. Lett. v.14 W. Helfrich;W. G. Schneider
  10. Appl. Phys. Lett. v.51 C. W. Tang;S. A. VanSlyke
  11. Jpn. J. Appl. Phys. v.27 C. Adachi;S. Tokito;T. Tsutsui;S. Saito
  12. テレビジョソ學會誌 v.44 安達千疲失;筒井哲夫;齊藤省吾
  13. 第37回 應用物理學關係漣合構演會豫稿集 古江敏彦;安達千疲失;筒井哲夫;齊藤省吾;又賀駿太郞;田代昌士
  14. Chem. Lett. N. Nobara;M. Hasegawa;C. Hosokawa;H. Tokailin;T. Kusumoto
  15. 制51回 應用物理學學術講演會豫橋集 仲田仁;脇本建夫;村山龍史;野村正治;佐藤義一
  16. 第51回 應用物理學學術講演會豫橋集 岩埼建二;安達千疲失;筒井哲夫;齊藤省吾
  17. Appl. Phys. Lett. v.55 no.15 C. Adachi;T. Tsutsui;S. Saito