Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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The Development of High Oxygen Pressures and the Stabilization of Unusual Oxidation States of Transition Metals

  • Gerard DEMAZEAU (Institut de Chimie de la Matiere Condensee Bordeaux I.C.M.C.B.-C.N.R.S.)
  • Published : 19980200
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Abstract

High oxygen pressures appear an important tool in Solid State Chemistry. Two main routes can be developed: (i) the stabilization of thermally unstable oxides, used as precursors, in order to open the synthesis of new materials, (ii) the stabilization of the highest oxidation states of transition metals. This paper is essentially devoted to this second research axis. The methodology developed for preparing new oxides containing Fe(Ⅴ), Ir(Ⅵ), high spin Fe(Ⅳ) and Cu(Ⅲ) is described.

Keywords

References

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