Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Photoreaction of 1-(o-Allyloxyphenyl)-2-pentamethyldisilanylethyne with Methanol or Acetone

  • Published : 1998.06.20
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Abstract

Irradiation of 1-(o-allyloxyphenyl)-2-pentamethyldisilanylethyne (2) in methanol yields two 1 : 1 photoaddition products (3 and 4) via silacyclopropene intermediate. Photolysis of (2) with acetone in deaerated methylene chloride yields site specific and regioselective 1: 1 adducts (7 and 8) via silacyclopropene and 1-sila-1,2-propadiene intermediate, respectively.

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References

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