Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Preparation and Thermal Properties of Enaminonitriles-Terminated Reactive Polymer Precursors

  • Published : 1998.03.20
Download PDF
⟨ Previous Next ⟩

Abstract

Various enaminonitriles-terminated reactive polymer precursors containing rigid aromatic and flexible alkyl units were prepared from the corresponding diamines and 1-chloro-1-phenyl-2,2-dicyanoethene (1). All the enaminonitriles-terminated precursors were characterized by spectroscopies and elemental analysis. They were highly soluble in DMF and NMP, and partially soluble in common organic solvents such as THF and acetone. They showed a large exotherm around 350 ℃ attributable to the thermal polymerization by crosslinking of the dicyanovinyl group. Upon heating the precursors, heat-resistant and insoluble network polymers were obtained. Thermogravimetric analyses of the precursors containing rigid aromatic moiety exhibited thermal stability with a 10% weight loss around 420-480 ℃ and 75-88% residual weight at 500 ℃ under nitrogen.

Keywords

References

  1. ASC Sym. Ser. 195 Cyclopolymerization and Polymers with Chain-Ring Structures Butler, G. B.;Cresta, J. E.
  2. ASC Sym. Ser. 282 Reactive Oligomers Spinelli, H. J.;Harris, F. W.
  3. Comprehensive Polymer Science v.5 Allen, G.;Bevington, J. C.
  4. Polym. J. v.26 Kim, Y. S.;Kim, B. G.;Gong, M. S.
  5. Macromolecules v.26 Cho, H. G.;Kim, B. G.;Choi, S. H.;Gong, M. S.
  6. Macromolecules v.22 Robello, D. R.;Moore, J. A.
  7. Makromol. Chem. Rapid Commun. v.12 Moon, H. S.;Kim, S. T.;Gong, M. S.
  8. Macromolecules v.26 Mehta, P. G.;Moore, J. A.
  9. Macromolecules v.26 Mehta, P. G.;Kim, S. Y.;Moore, J. A.
  10. Polym. J. v.25 Moon, H. S.;Kim, J. S.;Kim, C. B.;Gong, M. S.
  11. Macromolecules v.28 Shin, J. C.;Kim, T. M.;Gong, M. S.
  12. Polym. J. v.27 Ha, J. H.;Kim, C.;Gong, M. S.
  13. J. Polym. Sci., Part A: Polym. Chem. v.31 Mikroyannidis, J. A.
  14. J. Polym. Sci., Part A: Polym. Chem. v.29 Li, H.;Hsu, K. Y.;Chang, T. C.
  15. Macromol. Chem. Phys. Gong, M. S.;Park, W. S.