Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Vibronic Assignments of the $S_1 \rightarrow S_0$ Emission Spectrum of the Jet Cooled p-Fluorotoluene

  • Published : 1998.02.20
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Abstract

The p-fluorotoluene was vibronically excited in a jet with a buffer gas He in a corona excited supersonic expansion. The vibronic emission spectrum of the jet cooled p-fluorotoluene in the transition of S1 → S0 has been recorded with a Fourier transform spectrometer in the uv region. The spectrum observed was analyzed to obtain accurate vibrational frequencies in the ground electronic state by comparing with those reported previously. The origin of the low frequency sequence bands observed in this work was discussed. Also, the absence of significant intensity of hot band resulting from the excited vibrational states in the spectrum suggests extensive vibrational cooling in the source.

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References

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