Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Laser-Induced Fluorescence Spectroscopy of the $S_1-S_0 (^1B_2-^1A_1)$ Transition of Dimethyldiazirine

  • Published : 1998.10.20
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Abstract

The fluorescence excitation (FE) spectrum of the S1-S0 (1B2-1A1) transition of dimethyldiazirine cooled in supersonic jet expansions has been obtained. Dispersed fluorescence (DF) spectra have also been taken for some prominent features of the FE spectrum. Vibrational analyses of the FE and DF spectra with the help of an ab initio molecular orbital calculation lead to some new vibrational assignments and refined fundamental frequencies.

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References

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