DOI QR코드

DOI QR Code

인산 에스테르 반응 셀룰로오스 미립자의 활성화가 비수계 ER 유체의 전기유변학적 특성에 미치는 영향

The Effect of the Activation of Phosphoric Ester Cellulose Particles on the Electrotheological Properties of Anhydrous ER Fluids

  • 안병길 (한국과학기술연구원 Tribology Research Center) ;
  • 최웅수 (한국과학기술연구원 Tribology Research Center) ;
  • 권오관 (한국과학기술연구원 Tribology Research Center) ;
  • 문탁진 (고려대학교 재료금속공학부)
  • 발행 : 1998.09.01

초록

The electrorheological (ER) behavior of suspensions in silicone oil of phosphoric ester cellulose powder (average particle size: 17.77 $\mu$m) was investigated at room temperature with electric fields up to 2.5 KV/mm. For development of anhydrous ER suspensions using at wide temperature range, we aimed to know the effect of activation of phosphoric ester cellulose particles on the ER activities. As a first step, the anhydrous ER suspensions mixing with the phosphoric ester cellulose particles which were treated with 2M phosporic acid and 4M urea were measured. After activating the anhydrous ER suspensions at 12$0^{\circ}C$, not only the analysis of dispersing cellulose particles which were reacted by phosphoric ester but also the electrorheological characteristics of ER suspensions such as dielectric constant, current density, electrical conductivity and rheological properties were studied. From the experimental results, the activation of phosphoric ester cellulose particles had an influence on the ER properties of anhydrous ER suspensions. As the activation time went by, the size and number of dispersing particles, the electrical properties and the initial apparent viscosity $(η_0)$ of ER suspensions were increased till the activation time passed 5 hours. Also, it was possible, the electrorheological effect $($\tau$/$\tau$_0)$ of ER fluids was grown by the activation of phosphoric ester cellulose particles.

키워드

참고문헌

  1. J. Non-Newt. Fluid Mech. v.8 Shulman Z. P.;Gorodkin R. G.;Korobko E. V.;Gleb V. K.
  2. J. of Physics v.20 Induced Fibration Suspension Winslow W. M.
  3. U. S. Patent 2661596 Winslow W. M.
  4. Langmuir v.6 Materials and mechanism in electrorheology Block H.;Kelly J. P.;Qin A.;Watson T.
  5. J. Appl. Phys. v.38 Klass D. L.;Martinek T. W.
  6. J. Appl. Phys. v.38 Klass D. L.;Martinek T. W.
  7. Rheol. Acta v.23 Deinega Y. F.;Vinogradov G. V.
  8. IEEE Transactions on Electrical Insulation v.24 no.5 Electrorheology Therese C. Jordan;Montgonmery T. Shaw
  9. J. of Rheology v.34 no.4 An intrinsic mechanism for the activity of alumino-silicate based electrorheological materials Frank E. Filisko;Leonard H. Radzilowski
  10. U.S. Patent 4687589 Block H.;Kelly J. P.
  11. Chemically Modified Carbon Fibers Ermolenko I. N.;Lyubliner I. P.;Gulko N .V.
  12. J. Phys. Chem. v.66 Schwarz G.