The Effects of Particle Size Distribution on Electromagnetic Properties of Mn-Zn Ferrites

입자분포가 Mn-Zn Ferrite의 전자기적 물성에 미치는 경향

  • 강남규 (성균관대학교 재료공학과) ;
  • 서정주 (성균관대학교 재료공학과) ;
  • 신명승 (이수세라믹(주)) ;
  • 한명호 (성균관대학교 재료공학과)
  • Published : 1998.10.01

Abstract

The effects of particle size distribution have been investigated on the high frequency low loss Mn-Zn fer-rites. The particle size distribution was controlled by milling time. Zirconia ball and engineering plastic jar were employed to avoid iron contamination from the milling media. As increasing the milling time BET value was increased from 0.55 to 3.21m2/g and mean particle size was decreased from 2.1 $\mu\textrm{m}$ to 1.0$\mu\textrm{m}$ The large specific surface area of initial powder resulted in the high density of sintered core. However starting powders with high BET lead to inhomogeneous grain growth as well as poor electromagnetic pro-perties at sintering temperature above 1300$^{\circ}C$.

고주파 저손실 재질로 사용되는 Mn-Zn ferrites의 제조공정 중 입도분포제어가 전자기적 물성에 미치는 효과에 관하여 연구하였다. 입도분포는 분쇄시간을 변화시켜 제어하였으며 철의 유입을 막기위하여 지르코니아볼을 사용하였다. 분쇄시간이 증가함에 따라 입자크기는 2.1 $\mu\textrm{m}$에서 1.0$\mu\textrm{m}$로 감소하였으며, 비표면적은 0.55에서 3.21m2/g으로 증가하였다. 비표면적 값이 증가할수록 소결체의 밀도는 증가하였으며, 높은 비표면적을 가진 분말의 경우 1300$^{\circ}C$ 이 상의 고온에서 소결할 때 불균일한 미세구조와 과대입성장이 발생하였으며, 전자기적 물성감소가 나타났다.

Keywords

References

  1. J. Am. Ceram. Soc. v.66 no.10 Development of Magentic Ferrites:Control and Application on Losses K. Ishino;Y. Narumiya
  2. J. Am. Ceram. Soc. Bull. v.70 no.5 Processing of Mn-Zn Ferrites for High-Frequency Switch-Mode Power Supplies C.R. Hendricks;W.R. Amarakoon;D. Sullivan
  3. IEEE Trans. on Magn. v.MAG-15 no.6 Microstructure and Properties of Commercial Grade Manganese Zinc Ferrites H. Tsunekawa
  4. J. Appl. Phys. v.69 no.8 Microstructure and Physical Properties of Mn-Zn Ferrites for High Frequency Power Supplies E. Otsuki;S. Yamada;T. Otsuka;K. Shoji;T. Sato
  5. J. Am. Ceram. Soc. Bull. v.61 no.4 Dynamic Role of Zinc Oxide in the Sintering of Manganese Zinc Ferrites N.J. Hellicar;A. Sicignano
  6. J. Am. Ceram. Soc. v.54 no.6 Influence of Milled Powder Particle Size Distribution on the Microstructure and Electrical Properties of Sintered Mn-Zn Ferrites G.R. Chol
  7. NEC Res. Dev. v.8 Precipitation in Grain Boundaries of Ferrites and Their Electrical Resistivities-PartⅠ T. Akashi
  8. J. Appl. Phys. v.49 no.5 On the Origin of Core Losses in a Manganese Zinc Ferrite with Appreciable Silica Content G.C. Jain;B.K. Das;S. Kumari
  9. IEEE Trans. on Magn. v.MAG-11 no.5 Chart of PO₂ versus Temperature and Oxidation Degree for Mn-Zn Ferrites in the Composition Range: $50 (mol%) R. Morineau;M. Paulus