Impedance Properties of LSMC-YSZ Composite Cathode

LSMC-YSZ Composite 양극의 임피던스 특성

  • 김재동 (연세대학교 세라믹공학과) ;
  • 김구대 (한국과학기술연구원 세라믹공정센터) ;
  • 문지웅 (연세대학교 세라믹공학과) ;
  • 김창은 (연세대학교 세라믹공학과) ;
  • 이동아 (한국과학기술연구원 세라믹공정센터)
  • Published : 1998.09.01

Abstract

The polarization characteristics of the cathodes were discussed which were composed YSZ and ${(La_{0.75 }Sr_{0.25 })}_{0.95}Mn_{0.8 }Co_{0.2}O_3$ The three-phase-boundary length increased with the addition of YSN resulting in the minimum po-larization resistance at 60(LSMC) : 40(YSZ) wt% When LSMC-YSZ compoiste cathodes was sintered at $1200^{\circ}C$ minimum polarization resistance was observed and the capacitace increased with increasing sintering tem-perature.

YSZ와 계면반응하지 않는 ${(La_{0.75}Sr_{0.25})}_{0.95}Mn_{0.8 }Co_{0.2}O_3$에 전해질 물질인 YSZ를 첨가하여 양극의 분극특성을 고찰하였다. LSMC에 YSZ를 첨가함에 따라 삼상계면(Three Phase Boundary)이 증가하고, 분극저항이 감소하여 60 : 40wt% 비에서 최소값을 나타내었다. LSMC-YSZ composite 전극은 $1200^{\circ}C$ 에서 소결하여 최소의 분극저항을 나타내었고, 정전용량의 값은 소결온도의 증가에 따라 증가하였다.

Keywords

References

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