Co-firing of Solid Oxide Fuel Cell Using Pore Former

기공전구체를 이용한 고체전해질 연료전지의 동시소성 연구

  • 문지웅 (연세대학교 세라믹공학과) ;
  • 이홍림 (연세대학교 세라믹공학과) ;
  • 김구대 (한국과학기술연구원 세라믹공정연구센터) ;
  • 김재동 (연세대학교 세라믹공학과) ;
  • 이해원 (한국과학기술연구원 세라믹공정 연구센터)
  • Published : 1998.03.01

Abstract

Unite cell of soid oxide fuel cell (SOFC) that consists of a dense yttria-stabilized zirconia(YSZ) electrolyte a porous nickel-YSZ cermet anode and a porous strontium- doped lanthanum manganate(LSM) cathod was fabricated from using pore former through co-firing technique. Initial sintering shrinkage rates of each layer were identified for fabricating SOFC. Heterogenous sintering was very effective in tailoring shrinkage rate for three layers. The powder tailoring necessary for shrinkage rate matching are as follows ; electrolyte of 60% TZ8YS/ 40% TZ8Y mixture anode of 51wt% NiO/49 wt% (70wt% TZ8YS/30 wt% UT ZrO2) mixture and cathode of 80% LSM/20% UT ZrO2 mixture . The overall sintering shrinkage rate differences of three layers using these compositions were maintained in a few percent.

Keywords

References

  1. Proceeding of the 1st Eur. SOFC Forum Processing of SOFC Ceramic Components L.J. Gauckler;K. Sasaki;A. Mitterdorfer;M. Godickemeier;P. Bohac;UIF Bossel(ed.)
  2. Chemtech v.21 High-Temperature Fuel Cells;The Solid Oxide Fuel Cell N.Q. Minh
  3. Proceedings of the 3rd Intern. Symp. on SOFC Status of SOFC Development in Europe P. Zegers;S.C. Singhal(ed.);H. Iwahara(ed.)
  4. 요업학회지 v.34 no.10 Glycine-Nitrate Process를 이용하여 산화물 출발물질로부터 (La,Sr)MnO₃분말의 제조 김재동;문지웅;김구대;김창은
  5. J. Am. Ceram. Soc. v.76 no.3 N.Q. Mihn
  6. 한국요업학회지 v.31 no.9 다공성 세라믹스와 다공질층을 포함하는 적층체의 제조에 관한 연구 Ⅰ, 기공구조 이해원;윤복규
  7. Sintering and Related Phonomena The Sintering of Crystalline Oxides, Ⅰ. Interaction between Grain Boundaries and Pores W.D. Kingery;Francois;G.C. Kuczynski(ed.);N.A. Hooten(ed.);G.N. Gilbon(ed.)
  8. Advances in Ceramics v.12 Sinterability of ZrO₂and Al₂O₃Powders;The Role of Pore Coordination Number Distribution F.F. Lange;B.I. Davis;N. Claussen(ed.);M. Rule(ed.);A.H. Heuer(ed.)
  9. J. Am. Ceram. Soc. v.71 no.7 Effects of Pore Distribution on Microstructure Development Ⅱ. First and Second-Generation Pores J. Zaho;M.P. Harmer
  10. Acta Metall. v.34 no.7 Transient Stress in Bimodal Compacts During Sintering L.C. De Jonghe;M.N. Rahaman;C.-H. Hsueh
  11. Am. Ceram. Soc. Bull. v.66 no.2 Sintered Al₂O₃-SiC Whisker Composites T.N. Tiegs;P.F. Becker
  12. J. Am. Ceram. Soc. v.70 no.12 Effect of Rigid Inclusion on the Sintering of Glass Powder Compacts M.N. Rahaman;L.C. De Jonghe