Sontering behavior and dielectric properties $CaTiO_3-La(Zn_{1/2}Ti_{1/2})O_3$ microwave dielectrics

$CaTiO_3-La(Zn_{1/2}Ti_{1/2})O_3$ 마이크로파 유전체의 소결거동 및 유전특성

  • 김영신 (강릉대학교 세라믹공학과) ;
  • 윤상옥 (강릉대학교 세라믹공학과) ;
  • 박상엽 (강릉대학교 세라믹공학과) ;
  • 김경용 (한국과학기술연구원 세라믹스 연구부)
  • Published : 1998.06.01

Abstract

Sintering behavior and dielectric peroperties of $xCaTiO_3-La(Zn_{1/2}Ti_{1/2})O_3$ system were investigated for better understanding of the microwave dielectric materials. In $xCaTiO_3-(1-x)La(Zn_{1/2}Ti_{1/2})O_3$ systems, solid solution type was focused as a function of composition(x=0.4-0.6) and sintered density. With increasing the sintered density, the relative dielectric constant was decreased and Q value was increased and then saturated. In solid solution type, dielectric constant was increased with increasing $CaTiO_3$ content. In $0.5\;CaTiO_3-0.5\; La(Zn_{1/2}Ti_{1/2})O_3$ case, dielectric constant(=48) and temperature coefficient of resonace frequency$(=-1 ppm/^{\circ}C$) were obtained.

마이크로파 유전체로 응용되는 $xCaTiO_3-La(Zn_{1/2}Ti_{1/2})O_3$계의 소결시 고용조성 변화(x=0.4-0.6) 및 소결거동에 따른 유전특성에 조사하였다. 소결밀도가 감소함에 따라 유전상수는 감소하였으며 품질계수(Q)는 증가하다 일정한 값을 유지하였다. 고용체형의 경우 유전상수는 $CaTiO_3$조성 증가에 따라 증가하였다. $0.5\;CaTIO_3\;0.5\;La(Zn_{1/2}Ti_{1/2})O_3$의 경우 유전상수 48, 온도계수는 $-1ppm/^{\circ}C$를 나타내었다.

Keywords

References

  1. IEE Trans. Microwave Theory Tech. v.MTT-29 J. Plourde;C.L Ren
  2. Electron. Ceram. v.23 no.16 K. Hirada
  3. J. Am. Ceram. Soc. v.78 no.5 Jin-Ho Choy;Yang-Su Han;Jeong-Ho Sohn;Mitsuru Itoh
  4. J. Am. Ceram. Soc. H. Tamura;K. Wakino
  5. J. Am. Ceram. Soc. v.67 no.4 K. Wakino;K. Miniani;H. Tamura
  6. J. Am. Ceram. Soc. v.66 no.6 S. Kawasima;M. Nishida;I. Ueda;H. Ouchi
  7. J. Am. Ceram. Soc. v.74 no.6 S. Hirano;T. Hayashi;A. Hattori
  8. IRE Trans. Microwave Theory Tech. v.8 B.W. Hakki;P.D. Coleman
  9. J. Am. Ceram. Soc. v.54 no.3 A.E. Paladino
  10. J. Am. Ceram. Soc. v.78 no.11 A.B. Catalan;J.V. Mantese;A.L. Micheli;N.W. Schubring;C.A. Wong
  11. J. Am. Ceram. Soc. v.77 no.12 F. Kudesia;A.E. Michale;R.L. Snyder
  12. J. Kor. Ceram. Soc. v.33 no.10 W.M. Kim;J.D. Byun;H.T. Kim;Y.H. Kim
  13. J. Am. Ceram. Soc. v.79 no.6 V.M. Ferreira;J.L. Baptista
  14. J. Kor. Ceram. Soc. v.33 no.1 J.J. Lee;J.G. Park;T.S. Oh
  15. K.H. Hellwege;A.M. Hellwege
  16. エレトロセミクス no.春 少西 良弘