Journal of Photoscience

Korean Society of Photoscience (한국광과학회)
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PHOTOINDUCED ELECTRON TRANSFER REACTIONS OF 1,4-DIPHENYL-1,3-BUTADIYNE

  • Kim, Bang-Duk (Department of Chemistry, The Korea Advanced Institute of Science and Technology, Taejon 305-701) ;
  • Shim, Sang-Chul (Department of Chemistry, The Korea Advanced Institute of Science and Technology, Taejon 305-701)
  • Published : 1998.05.01
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Abstract

Irradiation of diphenylbutadiyne (DPB) in methanol with 9,10-dicyanoanthracene (DCA) yields four methanol adducts, two more than the products obtained in the absence of DCA. Laser flash photolysis studies indicate the reaction to proceed through a photoinduced electron transfer mechanism involving DPB cation radical and DCA anion radical.

Keywords

References

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